What is the change in internal energy for 5 moles of an ideal gas when it undergoes reversible compression from 100 K to 200 K?
(Given CV = 28 J K–1 mol–1)
1. | ΔU = 8kJ | 2. | ΔU = 14kJ |
3. | ΔU = 10kJ | 4. | ΔU = 2.8 kJ |
(i) | When liquid crystallizes into a solid, entropy increases. |
(ii) | When the temperature of a crystalline solid is raised from 0 K to 115 K then entropy increases. |
(iii) | 2 NaHCO3 (s) →Na2CO3 (s) +CO2(g)+H2O(g); Entropy increases. |
(iv) | H2(g)→2H(g) ; Entropy decreases. |
The average S–F bond energy in kJ mol–1 of SF6 is:
[The values of standard enthalpy of formation of
SF6(g), S(g), and F(g) are –1100, 275, and 80 kJmol–1 respectively.]
1. | 309 kJ mol–1 | 2. | 313 kJ mol–1 |
3. | 305 kJ mol–1 | 4. | 318 kJ mol–1 |
In an exothermic reaction, heat is evolved, and the system loses heat to the surrounding. The correct choice among the following for such a system are-
(a) qp will be negative
(b) will be negative
(c) qp will be positive
(d) will be positive
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
Consider a cycle followed by an engine (figure).
1 to 2 is isothermal,
2 to 3 is adiabatic,
3 to 1 is adiabatic.
Such a process does not exist, because:
(a) | heat is completely converted to mechanical energy in such a process, which is not possible. |
(b) | In this process, mechanical energy is completely converted to heat, which is not possible. |
(c) | curves representing two adiabatic processes don’t intersect. |
(d) | curves representing an adiabatic process and an isothermal process don't intersect. |
Choose the correct alternatives:
1. | (a), (b) | 2. | (a), (c) |
3. | (b), (c) | 4. | (c), (d) |
The entropy change for the melting of 'x' moles of ice at 273 K and 1 atm pressure is 28.80 cal K–1.
The value of 'x' is:
(Given: heat of fusion is 80 cal g–1)
1. | 4.32 mol | 2. | 8.56 mol |
3. | 10.36 mol | 4. | 5.46 mol |
1. | \(4\) | 2. | \(1\) |
3. | \(2\) | 4. | \(3\) |
Column I | Column II | ||
(i) | Spontaneous process | (a) | Isothermal and isobaric process |
(ii) | \(\Delta H^\circ\) | (b) | \(\Delta H<0 \) |
(iii) | \(\Delta T=0, \Delta P=0 \) | (c) | \(\Delta G<0 \) |
(iv) | Exothermic process | (d) | (Bond energy of reactant) - (Bond energy of product) |
I | II | III | IV | |
1. | c | d | a | b |
2. | b | a | c | d |
3. | d | b | c | d |
4. | a | d | b | c |
1. | \(\text{If}~P_1>P_2~\text{then}~T_1<T_2\) |
2. | \(\text{If}~V_2>V_1~\text{then}~T_2>T_1\) |
3. | \(\text{If}~V_2>V_1~\text{then}~T_2<T_1\) |
4. | \(\text{If}~P_1>P_2~\text{then}~V_1>V_2\) |
1. | \(2.29 \times 10^4 \) | 2. | \(2.29 \times 10^{-4} \) |
3. | \(-2.29 \times 10^4 \) | 4. | \(-2.29 \times 10^{-4} \) |