The complex that will exhibit maximum ionic conductivity in aqueous solution is:
1. K4[Fe(CN)6]
2. [Co(NH3)6]Cl3
3. [Cu(NH3)4]Cl2
4. [Ni(CO)4]
Identify the outer orbital complex among the following options.
(Atomic number Mn=25, Fe=26, Co=27, Ni=28)
1. [Fe(CN)6]4-
2. [Mn(CN)6]4-
3. [Co(NH3)6]3+
4. [Ni(NH3)6]2+
Pick out the correct statement with respect to [Mn(CN)6]3-.
1. It is sp3d2 hybridised and octahedral.
2. It is d2sp3 hybridised and octahedral.
3. It is sp3d2 hybridised and tetrahedral.
4. It is dsp2 hybridised and square planar.
A compound among the following has both fac-mer and optical isomers is:
1. [Co(NH3)5(NO3)]
2. [Co(en)3]3−
3. [Co(gly)3]
4. None of the above
The coordination entity among the following has the maximum magnitude of ∆ 0(CFSE in octahedral field).
1. [Co(H2O)6]3+
2. [Co(NH3)6]3+
3. [Co(CN)6]3-
4. [Co(C2O4)3]3-
The most stable complex among the following species is:
1.
2.
3.
4.
Assertion (A): | The relation between \(\Delta_t\) and \(\Delta_o\) is \(4\Delta_t = 9 \Delta_o\) . |
Reason (R): | \(\Delta_o\) is always greater than \(\Delta_t\) for same metal ion and ligand. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
1. | Ionisation isomerism |
2. | Co-ordination isomerism |
3. | Geometrical isomerism |
4. | Linkage isomerism |
Identify the system with the highest number of unpaired electrons among the following is:
1. d (Octahedral, low spin)
2. d (Tetrahedral)
3. d (Octahedral, low spin)
4. d (Octahedral)
The oxidation state of cobalt in the following molecule is:
1. 3
2. 1
3. 2
4. 0