Assertion (A): | An ideal solution obeys Raoult's law. |
Reason (R): | In an ideal solution, solute-solute as well as solvent-solvent, interactions are similar to solute-solvent interactions. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
A solution of sucrose (molar mass = 342 g mol–1) has been prepared by dissolving 68.5 g of sucrose in 1000 g of water. The freezing point of the solution obtained will be:
(kf for water = 1.86 K kg mol–1)
1. –0.372 oC
2. –0.520 oC
3. +0.372 oC
4. –0.570 oC
A 0.1 molal aqueous solution of a weak acid (HA) is 30 % ionized. If Kf for water is 1.86 °C/m, the freezing point of the solution will be:
1. | –0.24 °C | 2. | –0.18 °C |
3. | –0.54 °C | 4. | –0.36 °C |
pA and pB are the vapour pressure of pure liquid components, A and B, respectively of an ideal binary solution.
If XA represents the mole fraction of component A, the total pressure of the solution will be:
1. pA + XA (pB-pA)
2. pA + XA (pA-pB)
3. pB + XA (pB-pA)
4. pB + XA (pA-pB)
200 mL of an aqueous solution contains 1.26 g of protein. The osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar. The molar mass of protein will be:
(R = 0.083 L bar mol–1 K–1):
1. | 61038 g mol–1 | 2. | 51022 g mol–1 |
3. | 122044 g mol–1 | 4. | 31011 g mol–1 |
On dissolving sugar in water at room temperature solution feels cool to touch. Dissolution of sugar will be most rapid under the following case is:
1. Sugar crystals in cold water
2. Sugar crystals in hot water
3. Powdered sugar in cold water
4. Powdered sugar in hot water
Statement I: | At 20 °C, the molality of KCl solution is 'X' m, and on decreasing temperature to -10 °C molality remains unchanged. |
Statement II: | On changing temperature mass remains unchanged. |
1. | Both Statement I and Statement II are True. |
2. | Both Statement I and Statement II are False. |
3. | Statement I is True, and Statement II is False. |
4. | Statement I is False, and Statement II is True. |
The mole fraction of glucose (C6H12O6) in an aqueous binary solution is 0.1. The mass percentage of water in it to the nearest integer is:
1. | 44% | 2. | 49 % |
3. | 47 % | 4. | 41 % |
The value of Henry's law constant:
1. | Increases with increase in temperature. |
2. | Decreases with increase in temperature. |
3. | Increases with decrease in temperature. |
4. | Independent of temperature and depend only on pressure. |