Assertion (A): | The relation between \(\Delta_t\) and \(\Delta_o\) is \(4\Delta_t = 9 \Delta_o\) . |
Reason (R): | \(\Delta_o\) is always greater than \(\Delta_t\) for same metal ion and ligand. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
A metal ion present in vitamin B12 is:
1. | Fe(II) | 2. | Co(III) |
3. | Zn(II) | 4. | Ca(II) |
The complex that will exhibit maximum ionic conductivity in aqueous solution is:
1. K4[Fe(CN)6]
2. [Co(NH3)6]Cl3
3. [Cu(NH3)4]Cl2
4. [Ni(CO)4]
[Cr(NH3)6]3+ is paramagnetic ,while is diamagnetic because:
1. | Electrons in the 3d orbitals remain unpaired in |
2. | Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+ |
3. | Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+ |
4. | Electrons in the 3p orbitals remain unpaired in |
The correct splitting diagram of d orbitals in an octahedral crystal field is:
1. | 2. | ||
3. | 4. | None of these. |
Optical isomerism is exhibited by among the following is/are:
1. | [Cr(Ox)3]3+ | 2. | [PtCl2(en)2]2+ |
3. | [Cr(NH3)2Cl2en]+ | 4. | All of the above |
The correct statement among the following regarding \(FeCO_5\) is:
1. Tetranuclear
2. Mononuclear
3. Trinuclear
4. Dinuclear
Ethylene diaminetetraacetate (EDTA) ion is:
1. | Bidentate ligand with two "N" donor atoms |
2. | Tridentate ligand with three "N" donor atoms |
3. | Hexadentate ligand with four "O" and two "N'' donor atoms |
4. | Unidentate ligand |
Given below are two statements :
Statement I: | The identification of Ni2+ is carried out by dimethyl glyoxime in the presence of NH4OH. |
Statement II: | The dimethyl glyoxime is a bidentate neutral ligand. |
1. Statement I is false but Statement II is true.
2. Both Statement I and Statement II are false.
3. Statement I is true but Statement II is false.
4. Both Statement I and Statement II are true.