The azeotropic mixture of water and ethanol boils at 78.15 oC. When this mixture is distilled, it is possible to obtain-
1. Pure H2O
2. Pure C2H5OH
3. Pure H2O as well as pure C2HOH
4. Neither H2O nor C2H5OH in their pure state
The freezing point of depression constant (Kf ) of benzene is 5.12 K kg mol–1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is:
(rounded off up to two decimal places)
1. 0.80 K
2. 0.40 K
3. 0.60 K
4. 0.20 K
On dissolving sugar in water at room temperature solution feels cool to touch. Dissolution of sugar will be most rapid under the following case is:
1. Sugar crystals in cold water
2. Sugar crystals in hot water
3. Powdered sugar in cold water
4. Powdered sugar in hot water
Colligative properties are dependent on which of the following factors?
1. | The nature of the solute particles dissolved in the solution. |
2. | The number of solute particles in the solution. |
3. | The physical properties of the solute particles dissolved in the solution. |
4. | The nature of solvent particles. |
A solution that has the highest boiling point among the following is:
1. 1.0 M NaOH
2. 1.0 M Na2SO4
3. 1.0 M NH4NO3
4. 1.0 M KNO3
The value of Henry's law constant:
1. | Increases with increase in temperature. |
2. | Decreases with increase in temperature. |
3. | Increases with decrease in temperature. |
4. | Independent of temperature and depend only on pressure. |
40% (w/V) of NaCl solution (density = 1.14 g/ml) is equivalent to:
1.
2.
3.
4.
If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapor pressure to 80 %, the molar mass (in g mol–1) of the solute is:
[Molar mass of n-octane is 114 g mol–1]
1. | 40 | 2. | 60 |
3. | 80 | 4. | 20 |
Isotonic solutions have the same:
1. Vapour pressure
2. Freezing temperature
3. Osmotic pressure
4. Boiling temperature
A 0.1 molal aqueous solution of a weak acid (HA) is 30 % ionized. If Kf for water is 1.86 °C/m, the freezing point of the solution will be:
1. | –0.24 °C | 2. | –0.18 °C |
3. | –0.54 °C | 4. | –0.36 °C |