If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapor pressure to 80 %, the molar mass (in g mol–1) of the solute is:
[Molar mass of n-octane is 114 g mol–1]
1. | 40 | 2. | 60 |
3. | 80 | 4. | 20 |
Isotonic solutions have the same:
1. Vapour pressure
2. Freezing temperature
3. Osmotic pressure
4. Boiling temperature
A 0.1 molal aqueous solution of a weak acid (HA) is 30 % ionized. If Kf for water is 1.86 °C/m, the freezing point of the solution will be:
1. | –0.24 °C | 2. | –0.18 °C |
3. | –0.54 °C | 4. | –0.36 °C |
200 mL of an aqueous solution contains 1.26 g of protein. The osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar. The molar mass of protein will be:
(R = 0.083 L bar mol–1 K–1):
1. | 61038 g mol–1 | 2. | 51022 g mol–1 |
3. | 122044 g mol–1 | 4. | 31011 g mol–1 |
The positive deviations from Raoult’s law mean the vapour pressure is:
1. Higher than expected.
2. Lower than expected.
3. As expected.
4. None of the above
The type of inter-molecular interactions present in:
(a) | n-Hexane and n-octane | (i) | Van der Waal’s forces of attraction |
(b) | NaClO4 and water | (ii) | Ion-dipole interaction |
(iii) | Dipole-dipole interaction |
(a) | (b) | |
1. | (i) | (ii) |
2. | (ii) | (ii) |
3. | (i) | (iii) |
4. | (iii) | (iii) |
Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:
1. 1.85 × 10–5
2. 192 × 10–4
3. 178 × 10–5
4. 18.7 × 10–5
A solution that has the highest boiling point among the following is:
1. 1.0 M NaOH
2. 1.0 M Na2SO4
3. 1.0 M NH4NO3
4. 1.0 M KNO3
Colligative properties are dependent on which of the following factors?
1. | The nature of the solute particles dissolved in the solution. |
2. | The number of solute particles in the solution. |
3. | The physical properties of the solute particles dissolved in the solution. |
4. | The nature of solvent particles. |
On dissolving sugar in water at room temperature solution feels cool to touch. Dissolution of sugar will be most rapid under the following case is:
1. Sugar crystals in cold water
2. Sugar crystals in hot water
3. Powdered sugar in cold water
4. Powdered sugar in hot water