The specific conductance of a 0.1 M KCl solution at 23$°\mathrm{C}$ is 0.012 ${\mathrm{\Omega }}^{-1}{\mathrm{cm}}^{-1}$.
The resistance of the cell containing the solution at the same temperature was found to be 55 $\mathrm{\Omega }$. The cell constant will be:

1. 0.142 cm^–1
2. 0.66 cm^–1
3. 0.918 cm^–1
4. 1.12 cm^–1

For the cell, Ti/Ti⁺(0.001M)||Cu²⁺(0.1M)|Cu, ${\mathrm{E}}_{\mathrm{cell}}^{\mathrm{o}}$ $$at

25 $°$C is 0.83 V. E_cell can be increased :

1. By increasing [Cu²⁺]

2. By increasing [Ti⁺]

3. By decreasing [Cu²⁺]

4. None of the above.

The unit of specific conductance is:

During the electrolysis of a highly concentrated H₂SO₄ solution, which is released at the anode?

1. H₂

2. O₂

3. S₂O₈^2–

4. Both (1) & (3)

The electrode potential of Cu electrode dipped in 0.025 M CuSO₄ solution at 298 K is:

(standard reduction potential of Cu = 0.34 V)

1. 0.047 V

2. 0.293 V

3. 0.35 V

4. 0.387 V

Limiting molar conductivities, for the given solutions, are :

${\lambda }_m^0\left(H_{2}S{O}_4\right)= x$ $\mathrm{S }c{m}^2$ $mo{l}^{-1}$

${\lambda }_m^0\left(K_{2}S{O}_4\right)= y$ $\mathrm{S }c{m}^2$ $mo{l}^{-1}$

${\lambda }_m^0\left(C{H}_{3}COOK\right)= z$ $\mathrm{S }c{m}^2$ $mo{l}^{-1}$

From the data given above, it can be concluded that \(\lambda_m^0 \) in (\(S\ cm^2\ mol^{-1}\)) for CH₃COOH will be :
1. \(\mathrm{x-y+2z}\)       
2. \(\mathrm{x+y+z}\)          
3. \(\mathrm{x-y+z}\)       
4. \(\mathrm{{(x-y) \over 2}+z}\)          

The number of Faradays (F) required to produce 20 g of calcium from molten CaCl₂ (Atomic mass of Ca = 40 g mol^–1) is:

1. 2

2. 3

3. 4

4. 1

Molten sodium chloride conducts electricity due to the presence of: 

1. Free ions.

2. Free molecules.

3. Free electrons.

4. Atoms of sodium and chlorine.

Given that
I₂ + 2e¯ $\to$ 2I¯; E° = 0.54V
Br₂ + 2e¯ $\to$ 2Br¯; E° = 1.09V

Predict which of the following is true?

For a cell involving one electron ${\mathrm{E}}_{\mathrm{cell}}^{⊝}=0.\mathrm{59 }\mathrm{V}$ at 298 K.
The equilibrium constant for the cell reaction is :
\(\mathrm{[Given~ that~ \frac {2.303 ~RT}{F} = 0.059 ~V~ at~ T = 298 K]}\)

1. $1.0\times {10}^{30}$

2. $1.0\times {10}^2$

3. $1.0\times {10}^5$

4. $1.0\times {10}^{10}$