When the initial concentration of a reactant is doubled in a reaction, its half-life period is not affected. The order of the reaction will be:
1. 0
2. 1
3. 1.5
4. 2
A reaction having equal energies of activation for forward and reverse reaction has:
1. ΔG = 0
2. ΔH = 0
3. ΔH = ΔG = ΔS = 0
4. ΔS = 0
In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:
1. Rate = k[A][B]2
2. Rate = k[A]2[B]2
3. Rate = k[A][B]
4. Rate = k[A]2[B]
If 60% of a first-order reaction was completed in 60 min, 50% of the same reaction would be completed in approximately:
(log 4 = 0.60, log 5 = 0.69)
1. | 50 min | 2. | 45 min |
3. | 60 min | 4. | 40 min |
If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by:
1. t = 2.303/k
2. t = 0.693/k
3. t = 6.909/k
4. t = 4.606/k
The rate Constant of reaction A → B is 0.6 × 10–3 \(\mathrm{molL}^{-1} \mathrm{~S}^{-1}\). If the Concentration of A is 5M, then the concentration of B after 20 min is:
1. 1.08M
2. 3.60M
3. 0.36M
4. 0.72M
When the initial concentration of the reactant is doubled,
the half-life period of a zero-order reaction:
1. | is halved | 2. | is doubled |
3. | is tripled | 4. | remains unchanged |
The incorrect statement among the following is:
1. | The value of the equilibrium constant is changed in the presence of a catalyst in the reaction at equilibrium |
2. | Enzymes catalyse mainly bio-chemical reactions |
3. | Coenzymes increase the catalytic activity of the enzyme |
4. | The catalyst does not initiate any reaction |
A first-order reaction has a specific reaction rate of
10–2 sec–1. How much time will it take for 20 g of the reactant to reduce to 5 g?
1. | 138.6 sec | 2. | 346.5 sec |
3. | 693.0 sec | 4. | 238.6 sec |