For octahedral complex, the value of the 'spin only' magnetic moment for one of the following configuration is 2.84 BM. The correct one is:
1. d4 (in strong ligand field)
2. d4 (in weak ligand field)
3. d3 (in weak as well as in strong field)
4. d5 (in strong ligand field)
In the context of biological systems, coordination compounds play a crucial role;
identify the incorrect statement from the provided options.
1. | Cyanocobalamin is vitamin B12 and contains cobalt. |
2. | Haemoglobin is the red pigment of blood and contains iron. |
3. | Chlorophylls are green pigments in plants and contain calcium. |
4. | Carboxypeptidase - A is an enzyme and contains zinc. |
Consider the following complex ions P, Q and R,
P =
Q =
and R=
The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is:
1. R<Q<P
2. Q<R<P
3. R<P<Q
4. Q<P<R
The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes
CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is:
1. 3AgCl, 1AgCl, 2AgCl
2. 3AgCl, 2AgCl, 1AgCl
3. 2AgCl, 3AgCl, 1AgCl
4. 1AgCl, 3AgCl, 2AgCl
1. | Geometrical isomerism | 2. | Coordination isomerism |
3. | Ionization isomerism | 4. | Linkage isomerism |
Iron carbonyl, , is classified as:
1. | Tetranuclear | 2. | Mononuclear |
3. | Trinuclear | 4. | Dinuclear |
The hybridization involved in the complex is:
(Atomic number of Ni=28)
1.
2.
3.
4.
The IUPAC name of complex ion, [Fe(CN)6]3- is:
1. Hexacyanoiron(III) ion
2. Hexacyanitoferrate(III) ion
3. Tricynoferrate(III) ion
4. Hexacyanidoferrate(III) ion
An ion, among the following, that has a magnetic moment of 2.84 BM is:
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)
1. Ni2+
2. Ti3+
3. Cr2+
4. Co2+
Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:
1. | CoCl3. 3NH3 | 2. | CoCl3. 4NH3 |
3. | CoCl3. 5NH3 | 4. | CoCl3. 6NH3 |