The complex that is used as an anticancer agent is:
1. mer-[Co(NH3)3Cl3
2. cis-[PtCl2(NH3)2]
3. cis-K2[PtCl2 Br2]
4. Na2CoCl4
Pick out the correct statement with respect to [Mn(CN)6]3-.
1. It is sp3d2 hybridised and octahedral.
2. It is d2sp3 hybridised and octahedral.
3. It is sp3d2 hybridised and tetrahedral.
4. It is dsp2 hybridised and square planar.
A compound among the following has both fac-mer and optical isomers is:
1. [Co(NH3)5(NO3)]
2. [Co(en)3]3−
3. [Co(gly)3]
4. None of the above
The correct statement, among the following, regarding [Mn(CN)6]3- is:
1. It is sp3d2 hybridised and octahedral in shape
2. It is sp3d2 hybridised and tetrahedral in shape
3. It is d2sp3 hybridised and octahedral in shape
4. It is dsp2 hybridised and square planar in shape
The species that cannot act as an ambidentate ligand is:
1. | \(\mathrm{CN}^-\) | 2. | \(\mathrm{NO}^-_2\) |
3. | \(\mathrm{SCN}^-\) | 4. | \(\mathrm{NH_3}\) |
Consider the following complex ions P, Q and R,
P =
Q =
and R=
The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is:
1. R<Q<P
2. Q<R<P
3. R<P<Q
4. Q<P<R
In the context of biological systems, coordination compounds play a crucial role;
identify the incorrect statement from the provided options.
1. | Cyanocobalamin is vitamin B12 and contains cobalt. |
2. | Haemoglobin is the red pigment of blood and contains iron. |
3. | Chlorophylls are green pigments in plants and contain calcium. |
4. | Carboxypeptidase - A is an enzyme and contains zinc. |
For octahedral complex, the value of the 'spin only' magnetic moment for one of the following configuration is 2.84 BM. The correct one is:
1. d4 (in strong ligand field)
2. d4 (in weak ligand field)
3. d3 (in weak as well as in strong field)
4. d5 (in strong ligand field)
The complex with a square planar shape and dsp2 hybridization among the following is:
1. [Ni(CN)4]2-
2. [Cu(NH3)4]2+
3. [PtCl4]2-
4. All of these
The denticity of EDTA is:
1. | Monodentate | 2. | Hexadentate |
3. | Bidentate | 4. | Tridentate |