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MnO2 when fused with KOH and oxidized in the air gives a dark green compound X. In an acidic solution, X undergoes disproportionation to give an intense purple compound Y and MnO2.
The compounds X and Y, respectively are: 
1. Mn2Oand KMnO
2. K2MnO4 and KMnO4 
3. KMnO4 and K2MnO
4. KMnO4 and Mn2O7

Subtopic:  Chemistry of Mn and Cr Compounds |
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Dichromate ion shows the following equilibrium in an aqueous solution
\(Cr_{2}O_{7}^{2-} + H_{2}O\)  \(2CrO_{4}^{2-} + 2H^{+} \)
The value of X and Y, respectively, are:

1. 4 and 8

2. 8 and 4 

3. 7 and 7 

4. 4 and 4
Subtopic:  Chemistry of Mn and Cr Compounds |
 69%
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Gadolinium has a low value of third ionisation enthalpy because of:
1. High basic character 2. Small size
3. High exchange enthalpy 4. High electronegativity
Subtopic:  f-Block Elements- Properties & Uses |
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In the neutral or faintly alkaline medium, \(KMnO_4 \) oxidises iodide into iodate. The change in oxidation state of manganese in this reaction is from: 
1. +6 to +5  2. +7 to +4 
3. +6 to +4  4. +7 to +3
Subtopic:  d-Block Elements- Properties & Uses |
 75%
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NEET - 2022
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Match the statements given in List I with the corresponding element given in List II:

     List-I
(Characteristics)
List-II
(Elements)
(a) Element that exhibits +3 oxidation state only. (i) Mn
(b) An element that exhibits more number of oxidation states. (ii) Zn
(c) Element which is a reducing agent in its +2 oxidation state. (iii) Sc
(d) An element that is not considered as a transition element. (iv) Cr

Choose the correct answer from the options given below:
(a) (b) (c) (d)
1. (iii) (iv) (i) (ii)
2. (iv) (i) (ii) (iii)
3. (ii) (iv) (iii) (i)
4. (iii) (i) (iv) (ii)
Subtopic:  d-Block Elements- Properties & Uses |
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Identify the pair of Lanthanoides with one strong oxidant and one strong reductant:

1. Ce(IV), Tb(IV)  2. Yb(II), Eu(II)
3. Eu(IV), Lu(III) 4. Ce(IV), Eu(II)
Subtopic:  d-Block Elements- Properties & Uses |
 71%
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Assertion(A): Aquated copper (I) cation undergoes disproportionation as: 2Cu+(aq.)→Cu2+(aq.)+Cu
Reason(R): Hydration energy of Cu2+ is higher than that of Cu+ which compensates second ionization energy of Cu.
 
1. Both (A) and (R) are True and (R) is a correct explanation of (A).
2. Both (A) and (R) are True but (R) is not a correct explanation of (A).
3. (A) is True but the (R) is False.
4. (A) is False but (R) is True.
Subtopic:  d-Block Elements- Properties & Uses |
 87%
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The decrease in size from left to right in the actinoid series is greater and more gradual than that in the lanthanoid series due to:
1. 4f orbitals are penultimate
2. 4f orbitals have a greater shielding effect
3. 5f orbitals have a poor shielding effect
4. 5f orbitals have a greater shielding effect
Subtopic:  Lanthanoid & Actinoids Contraction |
 79%
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Statement 1: Highest oxidation state of a metal is exhibited in its oxide or fluoride only.
Statement 2: Both oxide and fluoride ions are able to oxidise metals.
 
1. Statement 1 is true, Statement 2 is false.
2. Statement 1 is false, Statement 2 is true.
3. Both Statements 1 and Statement 2 are true.
4. Both Statements 1 and Statement 2 are false.
Subtopic:  d-Block Elements- Properties & Uses |
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The correct electronic configuration of Ytterbium (Yb ,atomic no- 70)  is:

1. [Xe]4\(\)f125d26s2

2. [Xe]4f145d26s0

3. [Xe]4f145d16s1

4. [Xe]4f145d06s2
Subtopic:  f-Block Elements- Properties & Uses |
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