The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol–1. The dissociation constant of acetic acid is :
(\(\mathrm{\Lambda_{H^{+}}^{o} \ = \ 350 \ S \ cm^{2} \ mol^{-1} }\))
(\(\mathrm{\mathrm{\Lambda_{CH_{3}COO^{-}}^{o} \ = \ 50 \ S \ cm^{2} \ mol^{-1} }}\))
1. mol L–1
2. mol L–1
3. mol L–1
4. mol L–1
The variation of molar conductivity with the concentration of an electrolyte (X) in an aqueous solution is shown in the given figure.
The electrolyte X is:
1. | CH3COOH | 2. | KNO3 |
3. | HCl | 4. | NaCl |
Consider the following graph.
The strong electrolyte in the above graph is represented by:
1. X
2. Y
3. Both X and Y
4. Data given is not sufficient to predict.
The concentration of solution will change when it is placed in a container which is made of:
1. | Al | 2. | Cu |
3. | Ag | 4. | None |
Molar conductivities at infinite dilution of
NaCl, HCl, and are 126.4, 425.9, and 91.0 S cm2 mol–1 respectively.
for will be:
1. | \(180.5~S~cm^2~mol^{-1}\) | 2. | \(290.8~S~cm^2~mol^{-1}\) |
3. | \(390.5~S~cm^2~mol^{-1}\) | 4. | \(425.5~S~cm^2~mol^{-1}\) |
The potential of hydrogen electrode in contact with a solution with pH =10, is:
1. | −0.0591 V | 2. | −5.91 V |
3. | 0.0591 V | 4. | −0.591 V |
In a typical fuel cell, the reactants (R) and products (P) are:
1. | R = H2(g), O2(g); P = H2O2(l) |
2. | R = H2(g), O2(g); P = H2O(l) |
3. | R = H2(g), O2(g), C l2(g); P = HClO4(aq) |
4. | R = H2(g), N2(g); P = NH3(aq) |
The half-cell reaction at the anode during the electrolysis of aqueous sodium chloride solution is represented by :
1. Na+(aq) + e- ⟶ Na(s) ; \(E_{cell}^{o} \ = \ -2.71 \ V \)
2. 2H2O(l) ⟶ O2(g) + 4H+(aq) + 4e- ; \(E_{cell}^{o} \) = 1.23 V
3. H+(aq) + e- ⟶ \(\frac{1}{2}\)H2(g) ; \(E_{cell}^{o} \) = 0.00 V
4. Cl-(aq) ⟶ \(\frac{1}{2}\)Cl2(g) + e- ; \(E_{cell}^{o}\)
The cell constant of a conductivity cell-
1. | Changes with the change of electrolyte. |
2. | Changes with the change of concentration of electrolyte. |
3. | Changes with the temperature of the electrolyte. |
4. | Remains constant for a cell. |
Use the data given above to find out the most stable ion in its reduced form.
1. | Cl- | 2. | Cr3+ |
3. | Cr | 4. | Mn2+ |