For irreversible expansion of an ideal gas under isothermal condition, the correct option is :

1. $∆\mathrm{U}=0, ∆{\mathrm{S}}_{\mathrm{total}}\ne 0$

2. $∆\mathrm{U}\ne 0, ∆{\mathrm{S}}_{\mathrm{total}}=0$

3. $∆\mathrm{U}=0, ∆{\mathrm{S}}_{\mathrm{total}}=0$

4. $∆\mathrm{U}\ne 0, ∆{\mathrm{S}}_{\mathrm{total}}\ne 0$

Consider the following diagram for a reaction $\mathrm{A}\to \mathrm{C}$. 

The nature of the reaction is-

1. Exothermic

2. Endothermic

3. Reaction at equilibrium

4. None of the above

For the graph given below, it can be concluded that work done during the process shown will be-

At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol^–1 
H_2(g)+Br_2(g)$\to$2HBr_(g) and the bond energy of H₂ and Br₂ is 435 kJ mol^–1 and 192 kJ mol^–1 respectively, what is the bond energy (in kJ mol^–1) of HBr?

If for a certain reaction ${∆}_{r}H$ is 30 kJ mol^–1 at 450 K, the value of ${∆}_{r}S$ (in JK^–1 mol^–1) for which the same reaction will be spontaneous at the same temperature is:

The standard enthalpy of the formation of CH₃OH_(l) from the following data is:

The amount of heat needed to raise the temperature of 60.0 g of aluminium from 35°C to 55°C would be:

(Molar heat capacity of Al is \(24\) \(J\) \(\text{mol}^{- 1}\) \(K^{- 1}\))

The enthalpy of formation of all elements in their standard state is-

The correct statement among the following is: