Which graph represents the positive deviation of vapor pressure?
1. | 2. | ||
3. | 4. | None of the above |
The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The decreasing order of osmotic pressures of these solutions is:
1. | P2 > P3 > P1 | 2. | P3 > P1 > P2 |
3. | P2 > P1 > P3 | 4. | P1 > P2 > P3 |
The correct option for the value of vapour pressure of a solution at 45 C with benzene to octane in a molar ratio 3:2 is:
[At 45 C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]
1. 336 mm of Hg
2. 350 mm of Hg
3. 160 mm of Hg
4. 168 mm of Hg
At room temperature, a dilute solution of urea is prepared by dissolving 0.60 g of urea in 360 g of water. If the vapour pressure of pure water at this temperature is 35 mm Hg, lowering of vapour pressure will be:
(molar mass of urea = 60 g mol–1)
1. | 0.031 mmHg | 2. | 0.017 mmHg |
3. | 0.028 mmHg | 4. | 0.027 mmHg |
The mole fraction of glucose (C6H12O6) in an aqueous binary solution is 0.1. The mass percentage of water in it to the nearest integer is:
1. | 44% | 2. | 49 % |
3. | 47 % | 4. | 41 % |
Type of solution | Example |
a. Solid in gas | i. Aerated water |
b. Gas in liquid | ii. Smoke |
c. Liquid in solid | iii. Solution of hydrogen in palladium |
d. Gas in solid | iv. Amalgams |
a | b | c | d | |
1. | i | iii | iv | ii |
2. | ii | i | iv | iii |
3. | iii | i | iv | ii |
4. | iv | i | ii | iii |
To minimize the painful effects accompanying deep sea diving, oxygen diluted with less soluble helium gas is used as breathing gas by the divers. This is an example of the application of:
1. | Raoult's law | 2. | Henry's law |
3. | Ideal gas Equation | 4. | All of the above |
The solubility of a gas in a liquid decreases with an increase in temperature because:
1. | Dissolution of a gas in a liquid is an endothermic process. |
2. | Dissolution of a gas in a liquid is an exothermic process. |
3. | Gases are highly compressible. |
4. | All of the above. |
Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:
1. 1.85 × 10–5
2. 192 × 10–4
3. 178 × 10–5
4. 18.7 × 10–5
The type of inter-molecular interactions present in:
(a) | n-Hexane and n-octane | (i) | Van der Waal’s forces of attraction |
(b) | NaClO4 and water | (ii) | Ion-dipole interaction |
(iii) | Dipole-dipole interaction |
(a) | (b) | |
1. | (i) | (ii) |
2. | (ii) | (ii) |
3. | (i) | (iii) |
4. | (iii) | (iii) |