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The reaction(s) involved in the preparation of potassium dichromate from iron chromite ore is/are:

1. FeCr2O+ NaOH + O→ Na2CrO4 + Fe2O3 + H2O
2. Na2CrO+ H2SO4 (conc.) →
Na2Cr2O+ Na2SO+ H2O
3. Na2Cr2O+ KCl→ K2Cr2O7 + NaCl 
4. All of the above.

Subtopic:  Chemistry of Mn and Cr Compounds |
 86%
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For M2+/M, and M3+/M2+, the E° values of some metals are given in the table below:

Cr+2/Cr = -0.9 V Cr+3/Cr+2 = -0.4V
Mn+2/Mn = -1.2V Mn+3/Mn+2 = +1.5 V
Fe+2/Fe = -0.4V Fe+3/Fe+2 = +0.8 V

The correct inference(s) from the above data is/are: 

1. The increasing order of their stability is Mn3+< Fe3+< Cr3+   
2. The increasing order of the above-mentioned metals ability to get oxidized is: Fe < Cr < Mn
3. The increasing order of the above-mentioned metals ability to get oxidized is: Fe > Cr > Mn
4. Both 1 and 2 
Subtopic:  d-Block Elements- Properties & Uses |
 66%
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Consider the following graph.

Based on the graph above, it can be concluded that the element with a melting point higher than 3000 K will be:

1. Y 2. X
3. Z 4. None of the above
Subtopic:  d-Block Elements- Properties & Uses |
 91%
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Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of: 

1. Lanthanoid contraction
2. Having similar chemical properties
3. Belonging to the same group
4. Diagonal relationship
Subtopic:  d-Block Elements- Properties & Uses | Lanthanoid & Actinoids Contraction |
 89%
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The correct statement(s) about transition elements are:  

1. +2, and +3 oxidation states are more common for elements in the first transition series, while higher oxidation states are more common for the heavier elements.
2. The heavier transition elements form low-spin complexes only.
3. The atomic sizes of the elements of the first transition series are smaller than those of the heavier elements (elements of 2nd and 3r transition series).
4. All of the above.
Subtopic:  d-Block Elements- Properties & Uses |
 87%
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Match the List I with List II:

List I
(Metal ion )
List II
(Number of unpaired electrons)
i. Mn3+ a. 2
ii. Cr3+ b. 4
iii. V3+ c. 1
iv. Ti3+ d. 3

Choose the most appropriate options:
 
i ii iii iv
1. c d b a
2. b d a c
3. d b a c
4. b d c a
Subtopic:  d-Block Elements- Properties & Uses |
 82%
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Transition metals and their many compounds act as good catalysts due to :

1. Variable oxidation states 2. Unstable intermediate
3. Provide a suitable surface 4. All of the above
Subtopic:  d-Block Elements- Properties & Uses |
 82%
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The transition metals generally form coloured compounds due to :

1. Absorption of radiation to promote an electron .
2. Presence of ligands, the d-orbitals split up into two sets of orbitals.
3. Energy required to promote an electron in d subshell is low.
4. All of the above.

Subtopic:  d-Block Elements- Properties & Uses |
 88%
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The enthalpy of atomization of transition metals is high due to :

1. High effective nuclear charge

2. A large number of valence electrons

3. Very strong metallic bonds

4. All of the above

Subtopic:  d-Block Elements- Properties & Uses |
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The correct statement regarding the element silver(Ag) is: 

1. It is a hard metal.
2. It is not a transition element.
3. It has a partially filled d orbital in a +2 oxidation state. Thus, it is a transition element.
4. None of the above

Subtopic:  d-Block Elements- Properties & Uses |
 72%
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