Consider the given two statements:

Assertion (A):	KCN reacts with methyl chloride to give methyl isocyanide.
Reason (R):	\(CN^-\) is an ambident nucleophile.

Select the correct option:

1.	Both (A) and (R) are True and (R) is the correct explanation of (A).
2.	Both (A) and (R) are True but (R) is not the correct explanation of (A).
3.	(A) is True but (R) is False.
4.	(A) is False but (R) is True.

The correct match of column I (Reactions) with column II (Name of reactions) is:

Column I		Column II
A.		1.	Fittig reaction
B.		2.	Wurtz-Fittig reaction
C.		3.	Finkelstein reaction
D.		4.	Sandmeyer reaction

Codes:

 Match the structures given in Column-I with the IUPAC names in Column-II.

Column-I (Structure)		Column-II  (IUPAC Name)
A.		(i)	4-Bromopent-2-ene
B.		(ii)	4-Bromo-3-methylpent-2-ene
C.		(iii)	1-Bromobut-2-ene
D.		(iv)	1-Bromo-2-methylpent-2-ene

Codes:

Match the structures of compounds given in Column I with the classes of compounds given in Column II.

Column I		Column II
A.		1.	Aryl halide
B.		2.	Alkyl halide
C.		3.	Vinyl halide
D.		4.	Allylic halide

Codes:

Match the items in Column I and Column II.

Codes:

Arrange the compounds in increasing order of rate of reaction towards nucleophilic substitution.

1.  (i) < (ii) < (iii) 

2.  (ii) < (i) < (iii) 

3.  (iii) < (ii) < (i) 

4.  (i) < (iii) < (ii) 

Product ‘A’ in the following reaction is:

1.		2.
3.		4.

Compound(s) among the following with an asterisk (*) asymmetric carbon is/are:

1.  (a), (b), (c), (d)
2.  (a), (b), (c)
3.  (b), (c), (d)
4.  (a), (c), (d)

The most suitable reagent for the following conversion is:

\(\begin{align} CH_3CH_2CH_2CH_3 \rightarrow\ & CH_3CH_2CH_2CH_2Cl\ +\ \\ & CH_3CH_2CHClCH_3\end{align} \)

1. Cl₂/UV light

2. NaCl + H₂SO₄

3. Cl₂ gas in dark

4. Cl₂ gas in the presence of iron in dark

A compound that does not undergo S_N1 reaction with OH^- is:

1.		2.
3.		4.