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If a reaction A + B → C is exothermic to the extent of 30 kJ mol−1 and the forward reaction has an activation energy of 249 kJ mol−1, the activation energy for the reverse reaction in kJ mol-1 will be:

1. 324 2. 279
3. 40 4. 100

Subtopic:  Arrhenius Equation |
 93%
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5 g radioactive substance is taken in 1 L flask. How much substance will be left after 100 years, if half-life of substance in 25 years?

1. 2.5 g

2. 1.5 g

3. 0.625 g

4. 0.3125 g

Subtopic:  First Order Reaction Kinetics |
 83%
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For an lst order reaction, k = (8.5×105)e–15000K/T. The activation energy of the reaction is:  

1. 150 kJ/mol

2.  125 kJ/mol

3.  50 kJ/mol

4.  500 kJ/mol

Subtopic:  First Order Reaction Kinetics |
 78%
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Select the correct option based on statements below:

Assertion (A): For elementary reactions, the law of mass action and the rate of law expression are generally the same.
Reason (R): The molecularity of an elementary reaction is always one.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
 66%
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The rate constant of a reaction is
3 x 10-3 mol-2 L2s-1. Hence, the order is:

1. 1

2. Zero

3. 2

4. 3

Subtopic:  Order, Molecularity and Mechanism |
 81%
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For a zero-order reaction, the initial amount of reaction is 20 g and half-life is 30 minutes. The amount of reactant left after 60 minutes would be:

1. 5 g

2.  10 g

3.  2.5 g

4.  Zero

Subtopic:  Definition, Rate Constant, Rate Law |
 59%
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The rate constant of the given reaction-

R(g) \(\xrightarrow[]{\Delta }\) 2P(g) is 2.48 × 10–4 s–1.

A 1 : 1 molar ratio of R to P in the reaction mixture is attained after: 

1. 32 min

2. 27.3 min

3. 20 min

4. 0 min

Subtopic:  First Order Reaction Kinetics |
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An increase in the concentration of the reactants of a reaction leads to a change in:

1. Heat of reaction 2. Threshold energy
3. Collision frequency 4. Activation energy
Subtopic:  Arrhenius Equation |
 64%
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NEET - 2020
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When the temperature of a reaction increases from 300 K to 310 K, the rate of the reaction doubles. What is the activation energy for this reaction?

 \((R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \text { and } \log 2=0.301)\)

1. \(53.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 2. \(68.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \)
3. \(59.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 4. \(70.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Subtopic:  Arrhenius Equation |
 72%
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For a reaction, activation energy Ea=0 and the rate constant at 200 K is    1.6 × 106s-1. The rate constant at 400K will be [Given that gas constant, R=8.314 J K-1 mol-1]

1.  3.2 × 104 s-1
2. 1.6 × 106s-1
3. 1.6 × 103 s-1
4. 3.2 × 106 s-1

Subtopic:  Arrhenius Equation |
 77%
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NEET - 2019
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