Aluminium chloride in acidified aqueous solution forms a complex 'A'.
The formula of A and hybridisation state of Al in 'A' is respectively:

1. [Al(H₂O)₆]³⁺, sp³d²

2. [Al(H₂O)₄]³⁺, sp³

3. [Al(H2O)4]3+, dsp2

4. [Al(H₂O)]³⁺, d²sp³

A compound "X", upon reaction with H₂O, produces a colourless gas "Y" with a rotten fish smell.  Gas 'Y' is absorbed in a solution of CuSO₄ to give Cu₃P₂ as one of the products. The compound 'X' will be:

1. Ca₃P₂

2. ${\mathrm{NH}}_4\mathrm{Cl}$

3. ${\mathrm{As}}_2{\mathrm{O}}_3$

4. Ca₃(PO₄)₂

Among the following molecules, 

(i) $\stackrel{..}{X}e{O}_3$

(ii) $\stackrel{..}{X}eO{F}_4$

(iii) $\stackrel{..}{X}e{F}_6$

Those having the same number of lone pairs on Xe are

1. (i) and (ii) only

2. (i) and (iii) only

3. (ii) and (iii) only

4. (i), (ii) and (iii) only

In diborane, the two H-B-H angles are nearly-

1. $60°,$ $120°$

2. $97°,120°$

3. $97°,150°$

4. $120°,$ $180°$

The compound among the following with the lowest pK_a value is?

1. H₂O

2. H₂S

3. H₂Se

4. H₂Te

The incorrect statement among the following is -

1. ${\mathrm{PbX}}_2$ is more stable than ${\mathrm{PbX}}_4$

2. ${\mathrm{PbCl}}_4$ is less stable than ${\mathrm{SnCl}}_4$ but ${\mathrm{PbCl}}_2$ is more stable than ${\mathrm{SnCl}}_2$

3. ${\mathrm{PbCl}}_4$ is less stable than ${\mathrm{SnCl}}_4$

4. Pb(II) is a good reducing agent while Sn(II) is not

Incorrect order among the following is:

${\mathrm{H}}_3{\mathrm{BO}}_3$ is -

1. A Monobasic acid and a weak Lewis acid.

2. A Monobasic and a weak Bronsted acid..

3. A Monobasic and a strong Lewis acid.

4. A Tribasic and a weak Bronsted acid.

The correct structure of tribromo octoxide is:

1.
2.
3.
4.

False statement regarding PCl₅ is: