(a) | \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}-\mathrm{CH}_2-\mathrm{CH}_3 \) |
(b) | \(\left(\mathrm{CH}_3\right)_3 \stackrel{\oplus}{\mathrm{C}} \) |
(c) | \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}\mathrm{H} \) |
(d) | \( \text {CH}_3 \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_2\) |
(e) | \( \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_3 \) |
1. | e < d < c < a < b | 2. | d < e < c < a < b |
3. | a < e < d < c < b | 4. | e < d < c < b < a |
Assertion (A): | Chlorine is an electron-withdrawing group, yet it exhibits ortho- and para-directing behavior in electrophilic aromatic substitution. |
Reason (R): | Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
The correct statement about the SN1 reaction is:
1. | 100 % racemisation. |
2. | Inversion more than retention leads to partial racemisation. |
3. | 100 % retention. |
4. | 100 % Inversion. |
1. | 4 | 2. | 8 |
3. | 12 | 4. | 16 |
The correct statement regarding electrophile is :
1. | Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from another electrophile |
2. | Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a nucleophile |
3. | Electrophiles can be either neutral or positively charged species and can form a bond accepting a pair of electrons from a nucleophile |
4. | Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a nucleophile |
1. | 2. | ||
3. | 4. |
Hyperconjugation occurs among the following compounds:
1. | I only | 2. | II only |
3. | III only | 4. | I and III |
Two possible stereo-structures of CH3CHOH.COOH, that are optically active, called:
1. | Diastereomers | 2. | Atropisomers |
3. | Enantiomers | 4. | Mesomers |