The standard electrode potential (E°) values of Al3+/ Al, Ag+ / Ag, K+ / K, and Cr3+ / Cr are –1.66 V, 0.80 V, –2.93 V, & –0.79 V respectively. The correct decreasing order of the reducing power of the metals is:
| 1. | Ag > Cr > Al > K | 2. | K > Al > Cr > Ag |
| 3. | K > Al > Ag > Cr | 4. | Al > K > Ag > Cr |
Which of the following is the strongest oxidising agent?
1.
2.
3.
4.
The correct statement about the electrolysis of an aqueous solution of with Pt electrode is:
| 1. | Pt(s) gets oxidized at cathode whereas Ag + ( aq ) gets reduced at anode |
| 2. | Ag+ (aq) gets reduced at cathode and is oxidized at anode |
| 3. | Ag+ (aq) gets reduced at cathode whereas water is oxidized at anode |
| 4. | Ag (s) gets oxidized at cathode whereas H2O is oxidised at anode |
Standard reduction potentials of the half-reactions are given below:
The strongest oxidizing and reducing agents, respectively, are:
1. and
2. and
3. and
4. and
The correct statement about electrolysis of an aqueous solution of with Pt electrode is-
| 1. | Cu2+ ion reduced at the cathode; Cl- ion oxidized at the anode |
| 2. | Cu2+ ion reduced at the anode; Cl- ion oxidized at the cathode |
| 3. | Cu2+ ion reduced at the cathode; H2O ion oxidized at the anode |
| 4. | H2O ion reduced at the cathode; Cl- ion oxidized at the anode |
| 1. | \(\mathrm{2 {CuSO}_{4}({aq})+2 {Ag}({s}) → 2 {Cu}({s})+{Ag}_{2} {SO}_{4}({aq})} \) |
| 2. | \(\mathrm{{CuSO}_{4}({aq})+{Zn}({s})} \) \(\mathrm{→ {ZnSO}_{4}({aq})+{Cu}({s})} \) |
| 3. | \(\mathrm{{CuSO}_{4}({aq})+{Fe}({s})} \) \(\mathrm{→ {FeSO}_{4}({aq})+{Cu}({s})} \) |
| 4. | \(\mathrm{{FeSO}_{4}({aq})+{Zn}({s})} \) \(→ \mathrm{{ZnSO}_{4}({aq})+{Fe}({s})} \) |
Given that:
\(\begin{aligned} &E_{\mathrm{O}_{2} / \mathrm{H}_{2} \mathrm{O}}^{\Theta}=+1.23 \mathrm{~V} ; E_{S_{2} \mathrm{O}_{8}^{2-} / \mathrm{{SO}_{4}}^{-2}}=2.05 \mathrm{~V} \\ &E_{\mathrm{Br}_{2} / \mathrm{Br}^{-}}^{\Theta}=+1.09 \mathrm{~V} ; E_{A u^{3+} / A u}^{\Theta}=+1.4 \mathrm{~V} \end{aligned}\)
Which of the following is the strongest oxidizing agent?
1. \(\mathrm{S}_2 \mathrm{O}_8^{2-}\)
2. \(\mathrm{O}_2\)
3. \(A u^{3+}\)
4. \(B r_2\)
The reducing ability of the metals K, Au, Zn, and Pb follows the order
| 1. | K > Pb > Au > Zn | 2. | Pb > K > Zn > Au |
| 3. | Zn > Au > K > Pb | 4. | K > Zn > Pb > Au |