From the following bond energies:
H—H bond energy: 431.37 kJ mol^-1 
C=C bond energy: 606.10 kJ mol^-1 
C—C bond energy: 336.49 kJ mol^-1 
C—H bond energy: 410.50 kJ mol^-1 
Enthalpy for the reaction, 

will be:

Entropy decreases during:

1. Crystallization of sucrose from solution

2. Rusting of iron

3. Melting of ice

4. Vaporization of camphor

Given the reaction:
\(2 \mathrm{Cl}(\mathrm{~g}) \rightarrow \mathrm{Cl}_2(\mathrm{~g})\)
What are the values of \(∆\mathrm{H}\) and \(∆\mathrm{S}\), respectively?

1. \(\Delta \mathrm{H}=0, \Delta \mathrm{~S}=-\mathrm{ve}\)
2. \(\Delta \mathrm{H}=0, \Delta \mathrm{~S}=0\)
3. \(\Delta \mathrm{H}=-\mathrm{ve}, \Delta \mathrm{~S}=-\mathrm{ve}\)
4. \(\Delta \mathrm{H}=+\mathrm{ve}, \Delta \mathrm{~S}=+\mathrm{ve}\)

Under the isothermal condition, a gas at \(300 \mathrm{~K}\) expands from \(0.1 \mathrm{~L}\) to \(0.25 \mathrm{~L}\) against a constant external pressure of 2 bar. The work done by the gas is:
1. \(30 ~\mathrm {J} \)
2. \(-30 ~\mathrm{J} \)
3. \(5~ \mathrm{kJ}\)
4. \(25~ \mathrm{J}\)

Consider the following diagram for a reaction $\mathrm{A}\to \mathrm{C}$. 

The nature of the reaction is-

1. Exothermic

2. Endothermic

3. Reaction at equilibrium

4. None of the above

The enthalpy of formation of all elements in their standard state is-

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be-
(R = 8.314 J/mol K) (ln 7.5 = 2.01)

The amount of heat needed to raise the temperature of 60.0 g of aluminium from 35°C to 55°C would be:

(Molar heat capacity of Al is \(24\) \(J\) \(\text{mol}^{- 1}\) \(K^{- 1}\))