1. | exhibit +2 and +3 oxidation states. |
2. | have \(4 f^5 6 s^2 \) and \(4 f^6 6 s^2\) electronic configurations, respectively. |
3. | have \(4 f^7 6 s^2\) and \(4 f^8 6 s^2\) electronic configurations, respectively. |
4. | have same atomic radii. |
List-I (Element) |
List-II (Most Common oxidation state/s) |
||
A. | \(\mathrm{Fe}\) | I. | +2, +7 |
B. | V | II. | +3, +2 |
C. | \(\mathrm{Mn}\) | III. | +4 |
D. | \(\mathrm{Ti}\) | IV. | +5 |
A. | All the transition metals except scandium form MO oxides which are ionic. |
B. | The highest oxidation number corresponding to the group number on transition metal oxides is attained in Sc2O3 to Mn2O7. |
C. | Basic character increases from V2O3 to V2O4 to V2O5. |
D. | V2O4 dissolves in acids to give VO43-. |
E. | CrO is basic but Cr2O3 is amphoteric. |
1. | B and C only | 2. | A and E only |
3. | B and D only | 4. | C and D only |
Assertion (A): | Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. |
Reason (R): | There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. |
1. | (A) is correct but (R) is not correct |
2. | (A) is not correct but (R) is correct |
3. | Both (A) and (R) are correct and (R) is the correct explanation of (A) |
4. | Both (A) and (R) are correct but (R) is not the correct explanation of (A) |