| 1. | 1.5 moles | 2. | 7.5 moles | 
| 3. | 2.5 moles | 4. | 5.0 moles | 
| A. | \(Np(Z-93)\) | B. | \(Am(Z-95)\) | 
| C. | \(Ac(Z-89)\) | D. | \(Pa(Z-91)\) | 
| 1. | A > B > D > C | 2. | A > B > C > D | 
| 3. | B > A > D > C | 4. | D > B > A > C | 
| List-I (Element)  | 
			List-II (Most Common oxidation state/s)  | 
		||
| A. | \(\mathrm{Fe}\) | I. | +2, +7 | 
| B. | V | II. | +3, +2 | 
| C. | \(\mathrm{Mn}\) | III. | +4 | 
| D. | \(\mathrm{Ti}\) | IV. | +5 | 
| 1. | A-II, B-IV, C-I, D-III | 2. | A-IV, B-II, C-I, D-III | 
| 3. | A-II, B-I, C-IV, D-III | 4. | A-I, B-IV, C-II, D-III | 
| 1. | exhibit +2 and +3 oxidation states. | 
| 2. | have \(4 f^5 6 s^2 \) and \(4 f^6 6 s^2\) electronic configurations, respectively. | 
| 3. | have \(4 f^7 6 s^2\) and \(4 f^8 6 s^2\) electronic configurations, respectively. | 
| 4. | have the same atomic radii. | 
Which of the following ions have the same 'spin-only' magnetic moment?
| A. | Ti+3 | B. | Cr2+ | 
| C. | Mn2+ | D. | Fe2+ | 
| E. | Sc3+ | ||
Choose the most appropriate answer from the options given below:
| 1. | A and E only | 2. | B and C only | 
| 3. | A and D only | 4. | B and D only | 
| 1. | d5 to d2 configuration | 2. | d4 to d5 configuration | 
| 3. | d3 to d5 configuration | 4. | d5 to d4 configuration | 
| Assertion (A): | Ionisation enthalpies of early actinoids are lower than early lanthanoids. | 
| Reason (R): | Electrons entering 5f orbitals in actinoids experience greater shielding from the nuclear charge. | 
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). | 
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). | 
| 3. | (A) is True but (R) is False. | 
| 4. | (A) is False but (R) is True. | 
| Assertion (A): | Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. | 
| Reason (R): | There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. | 
| 1. | (A) is correct but (R) is not correct | 
| 2. | (A) is not correct but (R) is correct | 
| 3. | Both (A) and (R) are correct and (R) is the correct explanation of (A) | 
| 4. | Both (A) and (R) are correct but (R) is not the correct explanation of (A) | 
| A. | All the transition metals except scandium form MO oxides which are ionic. | 
| B. | The highest oxidation number corresponds to the group number in transition metal oxides is attained in Sc2O3 to Mn2O7.  | 
		
| C. | Basic character increases from V2O3 to V2O4 to V2O5. | 
| D. | V2O4 dissolves in acids to give VO43-. | 
| E. | CrO is basic, but Cr2O3 is amphoteric. | 
| 1. | B and C only | 2. | A and E only | 
| 3. | B and D only | 4. | C and D only |