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Q. No.For the reaction \(2 \mathrm{A} \rightleftharpoons \mathrm{B}+\mathrm{C}; ~\mathrm{K}_{\mathrm{c}}=4 \times 10^{-3}\).
At a given time, the composition of the reaction mixture is : \([\mathrm{A}]=[\mathrm{B}]=[\mathrm{C}]=2 \times 10^{-3} \mathrm{M} \text {. }\)
In light of the above facts, which of the following is correct?
At a given time, the composition of the reaction mixture is : \([\mathrm{A}]=[\mathrm{B}]=[\mathrm{C}]=2 \times 10^{-3} \mathrm{M} \text {. }\)
In light of the above facts, which of the following is correct?
| 1. | Reaction has a tendency to go in the forward direction. |
| 2. | Reaction has a tendency to go in the backward direction. |
| 3. | Reaction has gone to completion in the forward direction. |
| 4. | Reaction is at an equilibrium. |
Subtopic: Kp, Kc & Factors Affecting them | Le Chatelier's principle |
60%
Level 2: 60%+
NEET - 2024
Hints
In which of the following equilibria,\(\text{K}_\text{p}\) and \(\text{K}_\text{c}\) are NOT equal?
| 1. | \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\) |
| 2. | \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\) |
| 3. | \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\) |
| 4. | \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\) |
Subtopic: Kp, Kc & Factors Affecting them |
81%
Level 1: 80%+
NEET - 2024
Hints
Consider the following reaction in a sealed vessel at equilibrium:
\(2 \text{NO}_{(\text{g})} \rightleftharpoons \text{N}_{2(\text{g})} +\text{O}_{2\text{(g)}}\)
[Given: \(\text{N}_2=3.0 \times 10^{-3} \text{M}, \text{O}_2=4.2 \times 10^{-3} \text{M}\) and \(\text{NO}=2.8 \times 10^{-3} \text M\)]
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what will be the degree of dissociation (\(\alpha\)) of NO(g) at equilibrium?
1. 0.0889
2. 0.00717
3. 0.717
4. 0.00889
\(2 \text{NO}_{(\text{g})} \rightleftharpoons \text{N}_{2(\text{g})} +\text{O}_{2\text{(g)}}\)
[Given: \(\text{N}_2=3.0 \times 10^{-3} \text{M}, \text{O}_2=4.2 \times 10^{-3} \text{M}\) and \(\text{NO}=2.8 \times 10^{-3} \text M\)]
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what will be the degree of dissociation (\(\alpha\)) of NO(g) at equilibrium?
1. 0.0889
2. 0.00717
3. 0.717
4. 0.00889
Subtopic: Introduction To Equilibrium |
Level 3: 35%-60%
NEET - 2024
Hints
Consider the given reaction:
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
At equilibrium at \(500 \mathrm{~K},\) the concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):
1. 2.00
2. 2.6
3. 1.83
4. 3.4
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
At equilibrium at \(500 \mathrm{~K},\) the concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):
1. 2.00
2. 2.6
3. 1.83
4. 3.4
Subtopic: Kp, Kc & Factors Affecting them |
89%
Level 1: 80%+
NEET - 2024
Hints
For the equilibrium
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):
| 1. | \(1.493\) | 2. | \(2.494\times10^{-2}\) |
| 3. | \(3.0\times10^{-6}\) | 4. | \(2.494\times10^{-4}\) |
Subtopic: Kp, Kc & Factors Affecting them |
78%
Level 2: 60%+
NEET - 2024
Hints
Amongst the given option which of the following molecules/ion acts as a Lewis acid?
1. \(\text{OH}^- \)
2. \(\text{NH}_3 \)
3. \(\text H_2 \text O \)
4. \(\text{BF}_3 \)
1. \(\text{OH}^- \)
2. \(\text{NH}_3 \)
3. \(\text H_2 \text O \)
4. \(\text{BF}_3 \)
Subtopic: Acids & Bases - Definitions & Classification |
76%
Level 2: 60%+
NEET - 2023
Hints
The equilibrium concentration of the species in the reaction \(A+B \rightleftharpoons C+D\) are 2, 3, 10 and 6 mol L–1, respectively at 300 K. \(\Delta G^o\) for the reaction is:
(R = 2 cal/mol K)
(R = 2 cal/mol K)
| 1. | –13.73 cal | 2. | 1372.60 cal |
| 3. | –137.26 cal | 4. | –1381.80 cal |
Subtopic: Introduction To Equilibrium |
73%
Level 2: 60%+
NEET - 2023
Hints
Which combination of the following substances will result in the formation of an acidic buffer when mixed?
| 1. | Weak acid and it's salt with a strong base. |
| 2. | Equal volumes of equimolar solutions of weak acid and weak base. |
| 3. | Strong acid and its salt with a strong base. |
| 4. | Strong acid and its salt with a weak base. (The pKa of acid = pKb of the base) |
Subtopic: Buffer |
78%
Level 2: 60%+
NEET - 2023
Hints
For a weak acid HA, the percentage of dissociation is nearly 1% at equilibrium.
If the concentration of acid is 0.1 mol L-1, then the correct option for its Ka at the same temperature will be:
If the concentration of acid is 0.1 mol L-1, then the correct option for its Ka at the same temperature will be:
| 1. | \(1 \times 10^{-4}\) | 2. | \(1 \times 10^{-6} \) |
| 3. | \(1 \times 10^{-5} \) | 4. | \(1 \times 10^{-3} \) |
Subtopic: Ionisation Constant of Acid, Base & Salt |
68%
Level 2: 60%+
NEET - 2023
Hints
The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is:
[Given pKa of CH3COOH = 4.57]
1. 2.57
2. 5.57
3. 3.57
4. 4.57
[Given pKa of CH3COOH = 4.57]
1. 2.57
2. 5.57
3. 3.57
4. 4.57
Subtopic: pH calculation |
66%
Level 2: 60%+
NEET - 2022
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