1. | 2. | ||
3. | HF | 4. |
List I (Compound ) |
List II (Shape/geometry) |
||
A. | NH3 | I. | Trigonal Pyramidal |
B. | BrF5 | II. | Square planar |
C. | XeF4 | III. | Octahedral |
D. | SF6 | IV. | Square Pyramidal |
1. | B > A > D > C | 2. | B > A > C > D |
3. | D > C > B > A | 4. | A > C > B > D |
1. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\) \(\sigma^* 2 s<\left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma 2 p_z<\sigma^* 2 p_z\) |
2. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\) \(\left(\pi 2 p_x=\pi 2 p_y\right)< \) \(\sigma 2 p_z<\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \) |
3. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z<\) \( \left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \) |
4. | \( \sigma \text { 1s }<\sigma^* \text { 1s }\) \(<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z< \) \( \sigma^* 2 p_z<\left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right) \) |
1. | 1 | 2. | 3 |
3. | 2 | 4. | 4 |
1. | \(CH_4>H_2S>NH_3>HF \) |
2. | \(H_2S>NH_3>HF>CH_4 \) |
3. | \(NH_3>HF>CH_4>H_2~S \) |
4. | \(HF>NH_3>H_2S>CH_4\) |