| 1. | \(\mathrm{SF}_4, \mathrm{BrF}_5\) | 2. | \(\mathrm{SF}_4, \mathrm{ClF}_3\) |
| 3. | \(\mathrm{ClF}_3, \mathrm{XeF}_4\) | 4. | \(\mathrm{XeF}_4, \mathrm{BrF}_5\) |
| 1. | B > A > D > C | 2. | B > A > C > D |
| 3. | D > C > B > A | 4. | A > C > B > D |
| 1. | BF3 has non-zero dipole moment. |
| 2. | The dipole moment of NF3 is greater than that of NH3. |
| 3. | Three canonical forms can be drawn for \(\text{CO}_3^{2-}\) ion. |
| 4. | Three resonance structures can be drawn for ozone. |
| List-I (Compound) |
List-II (Shape/geometry) |
||
| A. | NH3 | I. | Trigonal Pyramidal |
| B. | BrF5 | II. | Square planar |
| C. | XeF4 | III. | Octahedral |
| D. | SF6 | IV. | Square Pyramidal |
| 1. | A-II, B-IV, C-III, D-I | 2. | A-III, B-IV, C-I, D-II |
| 3. | A-II, B-III, C-IV, D-I | 4. | A-I, B-IV, C-II, D-III |
| 1. | ![]() |
2. | ![]() |
| 3. | HF | 4. | ![]() |
| 1. | The \(\pi^*\) antibonding molecular orbital has a node between the nuclei. |
| 2. | In the formation of a bonding molecular orbital, the two electron waves of the bonding atoms reinforce each other. |
| 3. | Molecular orbitals obtained from \(2P_x\) and \(2P_y\) orbitals are symmetrical around the bond axis. |
| 4. | A \(\pi-\)bonding molecular orbital has larger electron density above and below the internuclear axis. |
| 1. | \(CH_4>H_2S>NH_3>HF \) |
| 2. | \(H_2S>NH_3>HF>CH_4 \) |
| 3. | \(NH_3>HF>CH_4>H_2~S \) |
| 4. | \(HF>NH_3>H_2S>CH_4\) |
| 1. | One | 2. | Three |
| 3. | Two | 4. | Four |