[Fe(H₂O)₆]³⁺ and [Fe(CN)₆]^3- differ in

(1) Magnetic nature

(2) Oxidation number

(3) Co-ordination number

(4) Structure

The number of geometrical isomers possible for a square planar complex $[\mathrm{Mabcd}{]}^{\pm \mathrm{n}}$ are

(1) 2

(2) 3

(3) 4

(4) 5

If excess of AgNO₃ solution is added to 100ml of 0.024M Solution of dichlorobis(ethylene diamine) cobalt(III) Choloride, how many moles of AgCl will be precipitated?

1. 0.0012

2. 0.0016

3. 0.0024

4. 0.0048

The species that cannot act as an ambidentate ligand is:

EAN of Fe in K₃[Fe(CN)₆] is

1. 34

2. 35

3. 36

4. 47

Which of the following has square planar structure?

1. [NiCl₄]^2-

2. [Ni(CO)₄]

3. [Ni(CN)₄]^2-

4. None of these

$\mathrm{Out}<mspace\; width="1em"></mspace>\mathrm{of}<mspace\; width="1em"></mspace>{\mathrm{TiF}}_6^{2-},<mspace\; width="1em"></mspace>{\mathrm{CoF}}_6^{3-},<mspace\; width="1em"></mspace>{\mathrm{Cu}}_2{\mathrm{Cl}}_2<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$ (At. no. Z of Ti = 22, CO = 27, Cu = 29, Ni = 28), the colourless species are

(a) ${\mathrm{TiF}}_6^{2-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{CoF}}_6^{3-}$

(b) ${\mathrm{Cu}}_2{\mathrm{Cl}}_2<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$$$

(c) ${\mathrm{TiF}}_6^{2-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{Cu}}_2{\mathrm{Cl}}_2$

(d) ${\mathrm{CoF}}_6^{3-}<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NiCl}}_4^{2-}$