The most preferred method for the preparation of pure alkyl chlorides from alcohols is:

1. \(\mathrm{R}-\mathrm{OH}+\mathrm{HCl} \xrightarrow{\mathrm{ZnCl}_2} \mathrm{R}-\mathrm{Cl}+\mathrm{H}_2 \mathrm{O}\)
2. \(\mathrm{R}-\mathrm{OH}+\mathrm{PCl}_5 \rightarrow \mathrm{R}-\mathrm{Cl}+\mathrm{POCl}_3+\mathrm{HCl}\)
3. \(\mathrm{R}-\mathrm{OH}+\mathrm{SOCl}_2 \rightarrow \mathrm{R}-\mathrm{Cl}+\mathrm{SO}_2+\mathrm{HCl}\)
4. \(\mathrm{R}-\mathrm{OH}+\mathrm{PCl}_3 \rightarrow \mathrm{R}-\mathrm{Cl}+\mathrm{H}_3 \mathrm{PO}_3\)
Subtopic:  Introduction and Physical Properties |
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The following compound would be classified as:

1. Vinylic halide 2. Benzylic halide
3. Aryl halide 4. Allylic halide
Subtopic:  Introduction and Physical Properties |
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Find the correct sequence of the bond enthalpy of the "C-X" bond among the following:

1. CH3-F < CH3-Cl > CH3-Br > CH3-I

2. CH3-Cl > CH3-F > CH3-Br > CH3-I

3. CH3-F < CH3-Cl < CH3-Br < CH3-I

4. CH3-F > CH3-Cl > CH3-Br > CH3-I

Subtopic:  Introduction and Physical Properties | Chemical Properties |
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The correct order of increasing C-X bond reactivity toward nucleophiles among the following is:

I      II     
III \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{X}\) IV \(\left(\mathrm{CH}_3\right)_2 \mathrm{CH}-\mathrm{X}\)
 
1. I < II < IV < III 2. II < III < I < IV
3. IV < III < I < II 4. III < II < I < IV
Subtopic:  Introduction and Physical Properties | Chemical Properties |
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