The correct representation of Potassium tris(oxalato) chromate(III) is:

1. K2Cr(C2O4)3
2. K3Cr(C2O4)3
3. K3Cr(C2O4)2
4. K2Cr(C2O4)4

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The complex that is used as an anticancer agent is:

1. mer-[Co(NH3)3Cl3         

2. cis-[PtCl2(NH3)2]

3. cis-K2[PtCl2 Br2]           

4. Na2CoCl4

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IUPAC name of [Pt(NH3)3(Br)(NO2)Cl]Cl is:

1. Triamminebromidochloridonitroplatinum(IV)Chloride
2. Triamminebromonitrocholoroplatinum(IV)Chloride
3. Triamminechlorobromonitroplatinum(IV)Chloride
4. Triamminenitrochlorobromoplatinum(IV)Chloride

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Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:

1. CoCl3. 3NH3 2. CoCl3. 4NH3
3. CoCl3. 5NH3 4. CoCl3. 6NH3
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The IUPAC name of [\(\mathrm {C r \left(en\right)_{3}}\)]\(\mathrm{C l}_{3}\) is:

1. Triethylenediaminechromium (III) chloride
2. Tris(ethylenediammine)chromium (II) chloride
3. Tris(ethylenediammine)chromium (III) chloride
4. Tris(ethylenediamine)chromium (II) chloride
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Two complexes, PtCl4·2NH3 and PtCl4·2KCl, do not give a precipitate of AgCl when treated with AgNO3. They give zero and three moles of ions, respectively, in solutions for one mole of the complex.  The structural formulae of both complexes are:

1. PtCl2NH32Cl2 and K2PtCl6 

2. PtCl4NH32 and K2PtCl2NH32 

3. PtCl4NH32 and K2PtCl6 

4. PtCl4·2NH3 and PtCl4·2KCl 

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The sum of the coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl is:

1. 9 2. 6
3. 7 4. 8
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2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

1. 3, 6 2. 3, 4
3. 2, 4 4. 4, 3
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The correct IUPAC name for Mn3(CO)12 is:

1. Dodecacarbonylmanganate(0)

2. Dodecacarbonylmanganate(II)

3. Dodecacarbonyltrimanganese(0)

4. Manganicdodecacarbonyl0)

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The species that cannot act as an ambidentate ligand is:

1. \(\mathrm{CN}^-\) 2. \(\mathrm{NO}^-_2\)
3. \(\mathrm{SCN}^-\) 4. \(\mathrm{NH_3}\)
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