If a reaction A + B → C is exothermic to the extent of 30 kJ mol−1 and the forward reaction has an activation energy of 249 kJ mol−1, the activation energy for the reverse reaction in kJ mol-1 will be:

1. 324 2. 279
3. 40 4. 100
Subtopic:  Arrhenius Equation |
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The correct statement about the rate constant of a reaction is:

1. Rate constant is nearly doubled with a rise in temperature by 10 °C 
2. Rate constant becomes half with a rise in temperature by 10 °C 
3. Rate constant remains unchanged with a rise in temperature by 10 °C 
4. None of the above
Subtopic:  Arrhenius Equation |
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The correct statement about X in the below mentioned graph:

1. X represents activation energy without catalyst.
2. X represents activation energy with catalyst.
3. X represents the enthalpy of the reaction without a catalyst.
4. X represents the enthalpy of the reaction with a catalyst.
Subtopic:  Arrhenius Equation |
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Select the correct option based on statements below:

Assertion (A): All collisions of reactant molecules lead to product formation.
Reason (R): Only those collisions in which molecules have the correct orientation and sufficient kinetic energy lead to the compound formation.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Arrhenius Equation |
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The nature of the reaction represented in the following graph is:

1. Endothermic reaction
2. Exothermic reaction
3. Both endothermic and exothermic reactions are represented by the same graph.
4. None of the above
Subtopic:  Arrhenius Equation |
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For a reaction A → B, the Arrhenius equation is given as  \(log_{e}k \ = \ 4 \ - \ \frac{1000}{T}\) the activation energy in J/mol for the given reaction will be:

1. 8314

2. 2000

3. 2814

4. 3412

Subtopic:  Arrhenius Equation |
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The correct representation of an exothermic reaction is:

1.  2.
3. 4. Both 1 and 2
Subtopic:  Arrhenius Equation |
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The rate constant, the activation energy, and the Arrhenius parameter of a chemical reaction at 25°C are 3.0×10-4 s-1104.4 kJ mol-1 and 6.0×1014s-1 respectively.
The value of the rate constant as T → ∞ will be:

1. 2.0 × 1018 s-1                                                  

2. 6.0 × 1014 s-1

3.                                                                    

4. 3.6 × 1030 s-1

Subtopic:  Arrhenius Equation |
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For A + B → C + D, H = -20 kJ mol-1 , the activation energy of the forward reaction is 85 kJ mol-1. The activation energy for the backward reaction is…. kJ mol-1.

1. 105 2. 85
3. 40 4. 65
Subtopic:  Arrhenius Equation |
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If H of a reaction is 100 kJ mol-1, then the activation energy for the forward reaction must be

1. Greater than 100 kJ mol-1

2. Less than 100 kJ mol-1

3. Equal to 100 kJ mol-1

4. None of the above.

Subtopic:  Arrhenius Equation |
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