Activation energy of any chemical reaction can be calculated if one knows the value of 
1. Probability of collision.
2. Orientation of reactant molecules during collision.
3. Rate constant at two different temperatures.
4. Rate constant at standard temperature.
Subtopic:  Arrhenius Equation |
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Which plot of In k vs \(\frac{\text{I}}{\text{T}}\) is consistent with Arrhenius equation?
1. 2.
3. 4.
Subtopic:  Arrhenius Equation |
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The rate of a reaction quadruples when temperature changes from 27°C to 57°C. Calculate the energy of activation.
Given R = 8.314 J K–1 mol–1, log 4 = 0.6021

1. 380.4 kJ/mol
2. 3.80 kJ/mol
3. 3804 kJ/mol
4. 38.04 kJ/mol
Subtopic:  Arrhenius Equation |
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Effective collisions are known to possess:

A: Energy greater than threshold energy.
B: Breaking of old bond in reactant.
C: Formation of new bond in product.
D: High activation energy.
E: Proper orientation.

Choose the correct answer from the options given below:
1. A, B, C, D only
2. A, B, C, E only
3. A, C, D, E only
4. B, C, D, E only
Subtopic:  Arrhenius Equation |
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Which of the following plot represents the variation of \(ln ~k\) versus \(\frac 1{T}\) in according with Arrhenius equation?
1. 2.
3. 4.
Subtopic:  Arrhenius Equation |
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Rate constants of a reaction at 500 K and 700 K are 0.04 \(s^{-1}\) and 0.14 \(s^{-1}\), respectively; then, activation energy of the reaction is: 
(Given : log 3.5 = 0.5441, R = 8.31 J \(K^{-1} \) \(\mathrm {mol}^{-1}\))
1. 182310 J 
2. 18500 J
3. 18219 J 
4. 18030 J
Subtopic:  Arrhenius Equation |
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Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion (A): A reaction can have zero activation energy.
Reason (R): The minimum extra amount of energy absorbed by reactant molecules so that their energy becomes equal to threshold value, is called activation energy.
In the light of the above statements choose the correct answer from the options given below:
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Arrhenius Equation |
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The plot of ln k vs \({1 \over T}\) for the following reaction 
\(2N_2O_5(g) \rightarrow 4NO_2 (g) + O_2(g) \) gives a straight line with the slope of the line equal to \(-1.0 \times 10^4 K \).
The activation energy for the reaction in J mol–1 is:
(Given R = 8.3 J K1 mol1)

1. \(4.0 \times 10^2 \) 2. \(4.0 \times 10^{-2} \)
3. \(8.3 \times 10^{-4} \) 4. \(8.3 \times 10^4 \)
Subtopic:  Arrhenius Equation |
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For a reaction AB, enthalpy of reaction is -4.2 kJmol-1 and enthalpy of activation is 9.6 kJmol-1. The correct potential energy profile for the reaction is:

1. 2.
3. 4.
Subtopic:  Arrhenius Equation |
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The slope of Arrhenius Plot (ln k v/s 1T) of the first-order reaction is -5×103 K. The value of Ea of the reaction is:

[Given R = 8.314 JK–1 mol–1]

1. 166 kJ mol–1 2. –83 kJ mol–1
3. 41.5 kJ mol–1 4. 83.0 kJ mol–1
Subtopic:  Arrhenius Equation |
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