The plot of osmotic pressure \((\pi)\) vs concentration \((mol L^{-1})\) for a solution gives a straight line with slope 25.73 L bar mol-1. The temperature at which osmotic pressure measurement is done is: \((\text {Use} \left.\mathrm{R}=0.083 \mathrm{~L} \mathrm{bar} \mathrm{mol}^{-1} \mathrm{~K}^{-1}\right)\)
1. 310°C
2. 25.73°C
3. 12.05 °C
4, 37°C
Subtopic:  Osmosis & Osmotic Pressure |
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Which of the following pair of aqueous solutions will have the same value of osmotic pressure? (Assume complete dissociation in aqueous solution)

1. \(0.1~ \mathrm{M}~ \mathrm{BaCl}_2 \text { and } 0.2 ~\mathrm{M} ~\mathrm{K}_2 \mathrm{SO}_4\)
2. \(0.1~ \mathrm{M}~ \mathrm{Na}_3 \mathrm{PO}_4 \text { and } 0.1 ~\mathrm{M}~ \mathrm{K}_2 \mathrm{SO}_4\)
3. \(0.2~ \mathrm{M}~ \mathrm{NaCl} \text { and } 0.1 ~\mathrm{M} ~\mathrm{K}_2 \mathrm{SO}_4\)
4. \(0.2 ~\mathrm{M} ~\mathrm{NaCl} \text { and } 0.1~ \mathrm{M} ~\mathrm{K}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]\)
Subtopic:  Osmosis & Osmotic Pressure |
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The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The decreasing order of osmotic the pressure of these solutions is:

1. P2 > P3 > P1 2. P3 > P1 > P2
3. P2 > P1 > P3 4. P1 > P2 > P3
Subtopic:  Osmosis & Osmotic Pressure |
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Isotonic solutions have the same:

1. Vapour pressure

2. Freezing temperature

3. Osmotic pressure

4. Boiling temperature

Subtopic:  Osmosis & Osmotic Pressure |
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200 mL of an aqueous solution contains 1.26 g of protein. The osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar. The molar mass of protein will be:

(R = 0.083 L bar mol–1 K–1):

1. 61038 g mol–1  2. 51022 g mol–1
3. 122044 g mol–1  4. 31011 g mol–1
Subtopic:  Osmosis & Osmotic Pressure |
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During osmosis, the flow of water through a semi-permeable membrane is:

1. From a solution having higher concentration only. 
2. From both sides of the semi-permeable membrane with equal flow rates.
3. From both sides of the semi-permeable membrane with unequal flow rates.
4. From a solution having lower concentration only.
Subtopic:  Osmosis & Osmotic Pressure |
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A solution contains a non-volatile solute of molecular mass M2. The molecular mass of solute in terms of osmotic pressure is:
where:

m2 → Mass of solute

V → Volume of solution

\(\pi\) → Osmotic pressure

1. M2=(m2π)VRT

2. M2=(m2V)RTπ

3. M2=(m2V)πRT

4. M2=(m2V)πRT

Subtopic:  Osmosis & Osmotic Pressure |
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From the colligative properties of a solution, which one is the best method for the determination of molecular weight of proteins & polymers:

1. Osmotic pressure

2. Lowering of vapour pressure 

3. Lowering of freezing point

4. Elevation in boiling point

Subtopic:  Osmosis & Osmotic Pressure |
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1 % (w/w) solution of a compound is isotonic with 5 % (w/w) sucrose (sugar) solution. The molecular weight of the compound will be:

1. 32.4 2. 68.4
3. 129.6 4. 34.2
Subtopic:  Osmosis & Osmotic Pressure |
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