A solution of urea (molar mass 56 g mol–1) boils at 100.18 ºC at atmospheric pressure. If Kf and Kb for water are 1.86 and 0.512 K kg mol–1 respectively, the above solution will freeze at:
1. –6.54 ºC
2. –0.654 ºC
3. 6.54 ºC
4. 0.654 ºC
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