The correct option for the value of vapour pressure of a solution at 45 °C with benzene to octane in a molar ratio 3:2 is:

[At 45 °C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]
1. 336 mm of Hg
2. 350 mm of Hg
3. 160 mm of Hg
4. 168 mm of Hg

Subtopic:  Raoult's Law |
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The mixture that shows positive deviation from Raoult's law is-

1. Benzene + Toluene

2. Acetone + Chloroform

3. Chloroethane + Bromoethane

4. Ethanol + Acetone

Subtopic:  Raoult's Law |
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For an ideal solution, the correct option is:

1. mix G=0 at constant T and P

2. mix S=0 at constant T and P

3. mix V0 at constant T and P

4. mix H=0 at constant T and P

Subtopic:  Raoult's Law |
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The correct statement regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour is :

1. Intermolecular attractive force between A-A and B-B are stronger than those between A-B
2. mixH = 0 at constant T and P
3. mixV = 0 at constant T and P
4. Intermolecular attractive forces between A-A and B-B are equal to those between A-B
Subtopic:  Raoult's Law |
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The incorrect statement among the following for an ideal solution is:

1. \(\Delta H_{\text{Mix}}=0\)
2. \(\Delta U_{\text{Mix}}=0\)
3. \(\Delta P=P_{\text{obs.}}-P_{\text{(Calculated by Raoult's law)}}=0\)
4. \(\Delta G_{\text{Mix}}=0\)
Subtopic:  Raoult's Law |
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Vapour pressure of chloroform \(\mathrm{(CHCl_3)}\) and dichloromethane \(\mathrm{(CH_2Cl_2)}\) at 25°C are 200 mmHg and 41.5 mmHg respectively. Vapour pressure of the solution was obtained by mixing 25.5 g of \(\mathrm{(CHCl_3)}\) and 40 g of \(\mathrm{(CH_2Cl_2)}\) at the same temperature will be: (Molecular mass of \(\mathrm{(CHCl_3)}\) = 119.5 u and molecular mass of \(\mathrm{(CH_2Cl_2)}\) = 85 u)

1. 90.40 mm Hg 2. 119.5 mm Hg 
3. 75 mm Hg  4. 173.9 mm Hg 
Subtopic:  Raoult's Law |
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A solution of acetone in ethanol:

1. Shows a negative deviation from Raoult's law
2. Shows a positive deviation from Raoult's law
3. Behaves like a near-ideal solution
4. Obeys Raoult's law
Subtopic:  Raoult's Law |
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The vapour pressure of two liquids 'P' and 'Q' are 80 and 60 torr, respectively. The total vapour pressure of the solution obtained by mixing 3 moles of P and 2 moles of Q would be:

1. 68 torr

2. 140 torr

3. 72 torr

4. 20 torr

Subtopic:  Raoult's Law |
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A solution has a 1:4 mole ratio of pentane to hexane.
The vapor pressures of the pure hydrocarbons at 20 ºC are
440 mm Hg for pentane and 120 mm Hg for hexane.
The mole fraction of pentane in the vapor phase would be:

1. 0.200 2. 0.478
3. 0.949 4. 0.786
Subtopic:  Dalton’s Law of Partial Pressure | Raoult's Law |
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The ideal solution indicates:

1. A – B attraction force is greater than A – A and B – B.
2. A – B attraction force is less than A – A and B – B.
3. Attraction force remains the same in A – A and B – B.
4. The volume of the solution is different from the sum of the volume of the solute and solvent.
Subtopic:  Raoult's Law |
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