Match the following reactants in Column I with the corresponding reaction products in Column II.

Column I

Column II

A. Benzene+Cl2AlCl3

1. Benzoic acid

B. Benzene+CH3ClAlCl3

2. Methyl phenyl ketone

C. Benzene+CH3COClAlCl3

3. Toluene

D. TolueneKMnO4/NaOH

4. Chlorobenzene

5. Benzene hexachloride

   

Options:  A   B   C   D 
1. 4  3  2  1 
2. 1 2 3 5
3. 5 4 3 2
4. 4 5 3 2
Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
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For an electrophilic substitution reaction, the presence of a halogen atom in the benzene ring:

A. Deactivates the ring by inductive effect
B. Deactivates the ring by resonance
C. Increases the charge density at ortho and para position relative to meta position by resonance.
D. Directs the incoming electrophile to meta position by increasing the charge density relative to ortho and para position.

Choose the correct option

1. (A, B)

2. (B, C)

3. (C, D)

4. (A, C)

Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
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In an electrophilic substitution reaction of nitrobenzene, the presence of nitro group:

(a) Deactivates the ring by inductive effect.
(b) Activates the ring by inductive effect.
(c) Decreases the charge density at ortho and para position of the ring relative meta position by resonance.
(d) Increases the charge density at meta position relative to the ortho and para positions of the ring by resonance.

Choose the correct option:
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)

Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
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