The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
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'The free energy change due to a reaction is zero when-

1. The reactants are initially mixed.

2.  A catalyst is added

3. The system is at equilibrium

4. The reactants are completely consumed

Subtopic:  Gibbs Energy Change |
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The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K

Subtopic:  Gibbs Energy Change |
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Hydrolysis of sucrose is given by the following reaction

Sucrose + H2 Glucose + Fructose

If the equilibrium constant (Kc) is 2×1013 at 300 K, the value of rG at the same temperature will be:

1. 8.314 J mol–1 K–1×300 K×ln (2×1013)

2. 8.314 J mol–1 K–1×300 K×ln (3×1013)

3. –8.314 J mol–1 K–1×300 K×ln (4×1013)

4. –8.314 J mol–1 K–1×300 K×ln (2×1013)

Subtopic:  Gibbs Energy Change |
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For a given reaction, H =35.5 kJ mol-1 and S = 83.6JK-1 mol-1. The reaction is spontaneous at:
(Assume that H and S do not vary with temperature)

1. T < 425 K 2. T > 425 K
3. All temperatures 4. T > 298 K
Subtopic:  Gibbs Energy Change |
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The equilibrium constant for a reaction is 10. The value of G° will be:

(R = 8.314 J K-1 mol-1 ; T = 300 K)

1. -5.74 kJ mol-1
2. - 5.74 J mol-1
3. + 4.57 kJ mol-1
4. -57.4 kJ mol-1

Subtopic:  Gibbs Energy Change |
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Given the Gibbs free energy change, \(\Delta \text G^\circ=+63.3~\text{kJ},\) for the following reaction, 
\(\mathrm{Ag_2 CO_3 (s) \rightarrow 2Ag^+ (aq) + CO^{2-}_3 (aq)}\)
\(\mathrm{K_{sp}}\) of \(\mathrm {Ag_2CO_3 (s) }\) in water at 25º C is:
(R = 8.314 JK–1 mol–1)
1. \(3.2 \times 10^{26}\)
2. \(8.0 \times 10^{-12}\)
3. \(2.9 \times 10^{-3}\)
4. \(7.9 \times 10^{-2}\)
Subtopic:  Gibbs Energy Change |
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The free energy change (G°) is negative when -

1. The surroundings do no electrical work on the system.

2. The surroundings do electrical work on the system.

3. The system does electrical work on the surroundings.

4. The system does no electrical work on the surroundings.

Subtopic:  Gibbs Energy Change |
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The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
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In the reaction, H and S both are positive. The condition under which the reaction would not be spontaneous is -

1. H>TS                             

2. S=H/T

3. H=TS                               

4. All of the above

Subtopic:  Gibbs Energy Change |
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