The enthalpy and entropy change for the reaction :

Br2 (l) + Cl2 (g) 2BrCl (g)

are 30 kJ mol-1 and 105 J K-1 mol-1 respectively.

The temperature at which the reaction will be in equilibrium is :

1. 285.7 K 2. 273.4 K
3. 450.9 K 4. 300.1 K
Subtopic:  Spontaneity & Entropy |
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Select the correct option based on statements below:
Assertion (A):  A liquid crystallizes into a solid and is accompanied by a decrease in entropy.
Reason (R):  In crystals, molecules organize in an ordered manner.
 
1.  Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Spontaneity & Entropy |
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Entropy decreases during:

1. Crystallization of sucrose from solution

2. Rusting of iron

3. Melting of ice

4. Vaporization of camphor

Subtopic:  Spontaneity & Entropy |
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Match the following process with entropy change:

Reaction Entropy change
A. A liquid vaporizes 1.  S=0
B. Reaction is non-spontaneous at all temperatures and H is positive 2.  S=positive
C. Reversible expansion of an ideal gas 3.  S=negative

Codes:

A B C
1. 2 3 1
2. 1 2 3
3. 1 3 2
4. 3 2 1
Subtopic:  Spontaneity & Entropy |
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For the reaction, , the value of ∆H and ∆S  are respectively:

1. H=0 , S=-ve

2. H=0 , S=0

3. H= -ve , S = -ve

4. H= +ve , S= +ve

Subtopic:  Spontaneity & Entropy |
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Match the following parameters with a description for spontaneity.

\(\Delta\) (Parameters) \(\Delta r\ H^⊝\) \(\Delta r\ S^⊝\)\(\Delta r\ G^⊝\) Description
A. + – + 1. Non-spontaneous at high temperature
B. – – + at high T 2. Spontaneous at all temperatures
C. – + – 3. Non-spontaneous at all temperatures

Codes:

A B C
1. 3 1 2
2. 1 2 3
3. 1 3 2
4. 3 2 1
Subtopic:  Spontaneity & Entropy |
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The entropy change in the isothermal reversible expansion of 2 moles of an ideal gas from 10 to 100 L at 300 K is

1. 42.3 J K-1

2. 35.8 J K-1

3. 38.3 J K-1

4. 32.3 J K-1

Subtopic:  Spontaneity & Entropy |
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Change in entropy is negative for:

1. Bromine (l)Bromine(g)

2. C(s) + H2O(g) CO(g) + H2(g)

3. N2(g,10 atm)N2(g,1 atm) 

4. Fe ( 1mol, 400 K)  Fe( 1mol, 300 K)

Subtopic:  Spontaneity & Entropy |
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1 mole of an ideal gas at 25°C is subjected to expand reversibly ten times of its initial volume. The change in entropy of expansion is:

1. 19.15 JK-1mol-1                         

2. 16.15 JK-1mol-1

3. 22.15 JK-1mol-1                         

4. None of the above

Subtopic:  Spontaneity & Entropy |
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Select the correct option based on statements below:
Assertion (A): Dissolution of sugar in water proceeds via an increase in entropy.
Reason (R): Entropy decreases, when an egg is boiled hard.
  
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Spontaneity & Entropy |
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