A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be-
(R = 8.314 J/mol K) (ln 7.5 = 2.01)

1. q = +208 J, w = -208 J 2. q = -208 J, w = -208 J
3. q = -208 J, w = + 208 J 4. q = +208 J, w = + 208 J
Subtopic:  First Law of Thermodynamics |
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Select the correct option based on statements below:
Assertion (A): Work done in an irreversible isothermal process at constant volume is zero.
Reason (R):  Work is assigned a negative sign during expansion and is assigned a positive sign during compression.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  First Law of Thermodynamics |
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For the graph given below, it can be concluded that work done during the process shown will be-

1. Zero 2. Negative
3. Positive 4. Cannot be determined
Subtopic:  First Law of Thermodynamics |
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Which of the following is correct for isothermal expansion of an ideal gas:

1. Wrev = Wirr

2. Wrev + Wirr = 0

3. Wrev > Wirr

4. qrev = qirr

Subtopic:  First Law of Thermodynamics |
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