The work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from pressure of 20 atmosphere to 10 atmosphere is :
( Given R = 2.0 cal K-1 mol-1)

1. -413.14 calories
2. 413.14 calories 
3. 100 calories
4. 0 calorie
 
Subtopic:  First Law of Thermodynamics |
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Choose the correct statement for the work done in the expansion and heat absorbed or released when 5 liters of an ideal gas at 10 atmospheric pressure isothermally expands into a vacuum until the volume is 15 liters:
1. Both the heat and work done will be greater than zero.
2. Heat absorbed will be less than zero and work done will be positive.
3. Work done will be zero and heat will also be zero.
4. Work done will be greater than zero and heat will remain zero.
Subtopic:  First Law of Thermodynamics |
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The work done when 1 mole of gas expands reversibly and isothermally from a pressure of 5 atm to 1 atm at 300 K is: ​
(Given log 5 = 0.6989 and R = 8.314 J K-1 mol-1)
1. zero J
2. 150 J
3. +4014.6 J
4. -4014.6 J

Subtopic:  First Law of Thermodynamics |
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One mole of an ideal gas at 300 K is expanded isothermally from 1 L to 10 L volume. \(\Delta U\) for this process is:
(Use R = 8.314 J K–1 mol–1)
1. 1260 J 2. 2520 J
3. 5040 J 4. 0 J
Subtopic:  First Law of Thermodynamics |
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An ideal gas expands isothermally from 10-3m3 to 10-2 m3 at 300 K against a constant pressure of 105 Nm-2. The work done by  the gas is:

1. +270 kJ 2. –900 J
3. +900 kJ 4. –900 kJ
Subtopic:  First Law of Thermodynamics |
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A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50 L to a final volume of 4.50L. The change in internal energy U of the gas in joules will be:
1. –500J
2. –505J
3. –506J
4. –508J

Subtopic:  First Law of Thermodynamics |
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Identify which of the following is the correct option for free expansion of an ideal gas under adiabatic condition.

1.   Δq0, T=0, W=0
2.   Δq=0, T=0, W=0
3.   Δq=0, T<0, W0
4.   Δq=0, T0, W=0

Subtopic:  2nd & 3rd Law of Thermodynamics | First Law of Thermodynamics |
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Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:

1. 3 Joules

2. 9 Joules

3. Zero

4. Infinite

Subtopic:  First Law of Thermodynamics |
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The work done during the expansion of a gas from a volume of 4 dm3 to 6 dm3 against a constant external pressure of 3 atm is:

1. –608 J

2. +304 J

3. –304 J

4. –6 J 

Subtopic:  First Law of Thermodynamics |
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The molar heat capacity of water at constant pressure, C, is 75 JK–1 mol–1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of the water is:

1. 1.2 K 2. 2.4 K
3. 4.8 K 4. 6.6 K
Subtopic:  First Law of Thermodynamics |
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