Statement I: | \(2 \mathrm{~F}\) electricity is required for the oxidation of 1 mole \(\mathrm{H}_2 \mathrm{O}\) to \(\mathrm{O}_2\). |
Statement II: | To get \(40.0 \mathrm{~g}\) of Aluminium from molten \(\mathrm{Al}_2 \mathrm{O}_3\) required electricity is \(4.44 \mathrm{~F}\). |
List I (Conversion) |
List II (Number of Faraday required) |
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A. | 1 mol of H2O to O2 | I. | 3F |
B. | 1 mol of \(MnO^-_4\) to \(Mn^{2+}\) | II. | 2F |
C. | 1.5 mol of \(Ca\) from molten \(CaCl_2\) | III. | 1F |
D. | 1 mol of FeO to Fe2O3 | IV. | 5F |
A: | This equation applies to both strong and weak electrolytes. |
B: | The value of the constant A depends upon the nature of the solvent. |
C: | The value of constant A is the same for both \(BaCl_2\) and \(MgSO_4\) |
D: | The value of constant A is the same for both \(BaCl_2\) and \(Mg(OH)_2\) |
1. | (A) and (B) only | 2. | (A), (B), and (C) only |
3. | (B) and (C) only | 4. | (B) and (D) only |
1. | 3.34 cm–1 | 2. | 1.34 cm–1 |
3. | 3.28 cm–1 | 4. | 1.26 cm–1 |
Assertion (A): | \(\Delta_{\mathrm{r}} \mathrm{G}=-\mathrm{nFE} _{\text {cell }}, \) value \(\mathrm{\Delta_rG }\) depends on n. | In equation
Reason (R): | \(\mathrm{E_{cell} }\) is an intensive property and \(\mathrm{\Delta_rG }\) is an extensive property. |
1. | (A) is False but (R) is True. |
2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
3. | Both (A) and (R) are True and (R) is not the correct explanation of (A). |
4. | (A) is True but (R) is False. |
1. | –200.27 kJ mol–1 | 2. | –212.27 kJ mol–1 |
3. | –212.27 J mol–1 | 4. | –200.27 J mol–1 |
Two half cell reactions are given below:
\(\begin{aligned} &\mathrm{{Co}^{3+}+e^{-} \rightarrow {Co}^{2+}, {E}_{{Co}^{2+} / {Co}^{3+}}^{\circ}=-1.81 {~V}} \\ &2 \mathrm{{Al}^{3+}+6 e^{-} \rightarrow 2 {Al}({s}), {E}_{{Al} / {Al}^{3+}}^{\circ}=+1.66 {~V}} \end{aligned} \)
The standard EMF of a cell with feasible redox reaction will be:
1. | +7.09 V | 2. | +0.15 V |
3. | +3.47 V | 4. | –3.47 V |