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Q. No.Which of the following ions have the same 'spin-only' magnetic moment?
A.
Ti+3
B.
Cr2+
C.
Mn2+
D.
Fe2+
E.
Sc3+
Choose the most appropriate answer from the options given below:
1.
A and E only
2.
B and C only
3.
A and D only
4.
B and D only
Subtopic: d-Block Elements- Properties & Uses |
66%
Level 2: 60%+
NEET - 2024
Hints
The pair of lanthanoid ions, consisting of elements which are diamagnetic, is:
1. Ce3+ and Eu2+
2. Gd3+ and Eu3+
3. Pm3+ and Sm3+
4. Ce4+ and Yb2+
1. Ce3+ and Eu2+
2. Gd3+ and Eu3+
3. Pm3+ and Sm3+
4. Ce4+ and Yb2+
Subtopic: f-Block Elements- Properties & Uses |
66%
Level 2: 60%+
NEET - 2024
Hints
The behaviour of samarium (Z=62) is very much like europium (Z=63), since both elements:
| 1. | exhibit +2 and +3 oxidation states. |
| 2. | have \(4 f^5 6 s^2 \) and \(4 f^6 6 s^2\) electronic configurations, respectively. |
| 3. | have \(4 f^7 6 s^2\) and \(4 f^8 6 s^2\) electronic configurations, respectively. |
| 4. | have the same atomic radii. |
Subtopic: f-Block Elements- Properties & Uses |
55%
Level 3: 35%-60%
NEET - 2024
Hints
Match List-I with List-II
Choose the correct answer from the options given below:
| List-I (Element) |
List-II (Most Common oxidation state/s) |
||
| A. | \(\mathrm{Fe}\) | I. | +2, +7 |
| B. | V | II. | +3, +2 |
| C. | \(\mathrm{Mn}\) | III. | +4 |
| D. | \(\mathrm{Ti}\) | IV. | +5 |
| 1. | A-II, B-IV, C-I, D-III | 2. | A-IV, B-II, C-I, D-III |
| 3. | A-II, B-I, C-IV, D-III | 4. | A-I, B-IV, C-II, D-III |
Subtopic: d-Block Elements- Properties & Uses |
83%
Level 1: 80%+
NEET - 2024
Hints
The number of moles of \(\mathrm{MnO}_4^{-}\) being reduced to \(\mathrm{Mn}^{2+}\) under acidic conditions by \(4.517 \times 10^{24}\) electrons are:
| 1. | 1.5 moles | 2. | 7.5 moles |
| 3. | 2.5 moles | 4. | 5.0 moles |
Subtopic: Chemistry of Mn and Cr Compounds |
52%
Level 3: 35%-60%
NEET - 2024
Hints
The common oxidation state shown by actinoids is +3 with the other oxidation states being +4, +3, +6, and +7. The number of oxidation states shown by the following elements decrease in the order:
Choose the correct answer from the options given below:
| A. | \(Np(Z-93)\) | B. | \(Am(Z-95)\) |
| C. | \(Ac(Z-89)\) | D. | \(Pa(Z-91)\) |
| 1. | A > B > D > C | 2. | A > B > C > D |
| 3. | B > A > D > C | 4. | D > B > A > C |
Subtopic: f-Block Elements- Properties & Uses |
55%
Level 3: 35%-60%
NEET - 2024
Hints
The E° value for the Mn3+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to change of:
| 1. | d5 to d2 configuration | 2. | d4 to d5 configuration |
| 3. | d3 to d5 configuration | 4. | d5 to d4 configuration |
Subtopic: d-Block Elements- Properties & Uses |
72%
Level 2: 60%+
NEET - 2024
Hints
Given below are two statements:
| Assertion (A): | Ionisation enthalpies of early actinoids are lower than early lanthanoids. |
| Reason (R): | Electrons entering 5f orbitals in actinoids experience greater shielding from the nuclear charge. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Subtopic: f-Block Elements- Properties & Uses |
Level 3: 35%-60%
NEET - 2023
Hints
| Assertion (A): | Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. |
| Reason (R): | There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. |
| 1. | (A) is correct but (R) is not correct |
| 2. | (A) is not correct but (R) is correct |
| 3. | Both (A) and (R) are correct and (R) is the correct explanation of (A) |
| 4. | Both (A) and (R) are correct but (R) is not the correct explanation of (A) |
Subtopic: d-Block Elements- Properties & Uses |
73%
Level 2: 60%+
NEET - 2023
Hints
Which of the following statements is incorrect?
Choose the correct answer from the options given below:
| A. | All the transition metals except scandium form MO oxides which are ionic. |
| B. | The highest oxidation number corresponds to the group number in transition metal oxides is attained in Sc2O3 to Mn2O7. |
| C. | Basic character increases from V2O3 to V2O4 to V2O5. |
| D. | V2O4 dissolves in acids to give VO43-. |
| E. | CrO is basic, but Cr2O3 is amphoteric. |
| 1. | B and C only | 2. | A and E only |
| 3. | B and D only | 4. | C and D only |
Subtopic: d-Block Elements- Properties & Uses |
53%
Level 3: 35%-60%
NEET - 2023
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