The E° value for the Mn3+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to change of: 

1. d5 to dconfiguration
2. d4 to dconfiguration
3. dto dconfiguration
4. d5 to dconfiguration

Subtopic:  d-Block Elements- Properties & Uses |
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Which of the following ions have the same 'spin-only' magnetic moment?
A. Ti+3
B. Cr2+
C. Mn2+
D. Fe2+
E. Sc3+
Choose the most appropriate answer from the options given below:
1. A and E only
2. B and C only
3. A and D only
4. B and D only

Subtopic:  d-Block Elements- Properties & Uses |
 65%
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The pair of lanthanoid ions, consisting of elements which are diamagnetic, is:

1. Ce3+ and Eu2+
2. Gd3+ and Eu3+
3. Pm3+ and Sm3+
4. Ce4+ and Yb2+
Subtopic:  f-Block Elements- Properties & Uses |
 65%
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The behaviour of samarium (Z=62) is very much like europium (Z=63), since both elements:
1. exhibit +2 and +3 oxidation states.
2. have \(4 f^5 6 s^2 \) and \(4 f^6 6 s^2\) electronic configurations, respectively.
3. have \(4 f^7 6 s^2\) and \(4 f^8 6 s^2\) electronic configurations, respectively.
4. have the same atomic radii.
Subtopic:  f-Block Elements- Properties & Uses |
 56%
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Match List-I with List-II 
List-I
(Element)
List-II
(Most Common oxidation state/s)
A.  \(\mathrm{Fe}\) I.  +2, +7 
B.  V II. +3, +2 
C.  \(\mathrm{Mn}\) III. +4
D.  \(\mathrm{Ti}\) IV.  +5
Choose the correct answer from the options given below:
 
1. A-II, B-IV, C-I, D-III 2. A-IV, B-II, C-I, D-III
3. A-II, B-I, C-IV, D-III 4. A-I, B-IV, C-II, D-III
Subtopic:  d-Block Elements- Properties & Uses |
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The number of moles of \(\mathrm{MnO}_4^{-}\) being reduced to \(\mathrm{Mn}^{2+}\) under acidic conditions by \(4.517 \times 10^{24}\) electrons are:
1. 1.5 moles 2. 7.5 moles
3. 2.5 moles 4. 5.0 moles
Subtopic:  Chemistry of Mn and Cr Compounds |
 51%
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The common oxidation state shown by actinoids is +3 with the other oxidation states being +4, +3, +6, and +7. The number of oxidation states shown by the following elements decrease in the order:
A. \(Np(Z-93)\)
B. \(Am(Z-95)\)
C. \(Ac(Z-89)\)
D. \(Pa(Z-91)\)
Choose the correct answer from the options given below:
1. A > B > D > C
2. A > B > C > D
3. B > A > D > C
4. D > B > A > C
Subtopic:  f-Block Elements- Properties & Uses |
 55%
NEET - 2024
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Given below are two statements: 
Assertion (A): Ionisation enthalpies of early actinoids are lower than for early lanthanoids.
Reason (R): Electrons are entering 5f orbitals in actinoids which experience greater shielding from nuclear charge.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  f-Block Elements- Properties & Uses |
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Assertion (A): Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. 
Reason (R): There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. 
 
1. (A) is correct but (R) is not correct 
2. (A) is not correct but (R) is correct
3. Both (A) and (R) are correct and (R) is the correct explanation of (A) 
4. Both (A) and (R) are correct but (R) is not the correct explanation of (A) 
Subtopic:  d-Block Elements- Properties & Uses |
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Which of the following statements is incorrect?
A. All the transition metals except scandium form MO oxides which are ionic.
B. The highest oxidation number corresponds to the group number
in transition metal oxides is attained in Sc2O3 to Mn2O7
C. Basic character increases from V2O3 to V2O4 to V2O5
D. V2O4 dissolves in acids to give VO43-
E. CrO is basic, but Cr2O3 is amphoteric. 
Choose the correct answer from the options given below: 
1. B and C only 2. A and E only 
3. B and D only  4. C and D only
Subtopic:  d-Block Elements- Properties & Uses |
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