Match the bond line structures of hydrocarbons given in List-I with the corresponding boiling points given in List-II.
| List-I (Compound) | List-II (Boiling point in K) | ||
| (a) | (i) | 300.9 | |
| (b) | |
(ii) | 282.5 |
| (c) | |
(iii) | 309.1 |
| (d) | (iv) | 341.9 |
| (a) | (b) | (c) | (d) | |
| 1. | (i) | (iv) | (iii) | (ii) |
| 2. | (iii) | (i) | (iv) | (ii) |
| 3. | (iii) | (iv) | (i) | (ii) |
| 4. | (iv) | (i) | (ii) | (iii) |
The compound obtained by addition of water to an alkyne having more than two carbons, in the presence of \(\mathrm{HgSO_4 }\) and dilute \(\mathrm{H_2SO_4}\) at 333K, is:
1. A vicinal diol
2. An aldehyde
3. An alcohol
4. A ketone
| 1. | Pent-2-ene | 2. | 3-Methylbut-1-ene |
| 3. | 2-Methylbut-1-ene | 4. | 2-Methylbut-2-ene |
| 1. | 2. | ||
| 3. | 4. |
| i. | ii. | ||
| iii. | iv. | ||
| v | vi | ||
| vii |
| 1. | 5 | 2. | 4 |
| 3. | 6 | 4. | 2 |
| 1. | 33% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 2. | 50% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
| 3. | 100% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 4. | 100% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
| 1. | 109° | 2. | 120° |
| 3. | 180° | 4. | 360° |