Match each item in Column I with one in Column II and select the correct match from the codes given
List-I | List-II | ||
(a) | Separation of aniline-water mixture | (i) | Fractional distillation |
(b) | Separation of aniline-chloroform mixture | (ii) | Distillation under reduced pressure |
(c) | Separation of glycerol from spent-lye | (iii) | Distillation |
(d) | Separation of different fractions of crude oil | (iv) | Steam distillation |
(a) | (b) | (c) | (d) | |
1. | (i) | (iii) | (ii) | (iv) |
2. | (iv) | (i) | (iii) | (ii) |
3. | (iv) | (ii) | (iii) | (i) |
4. | (iv) | (iii) | (ii) | (i) |
1. | sp2 and sp3 | 2. | sp2 and sp2 |
3. | sp3 and sp2 | 4. | sp3 and sp3 |
Assertion (A): | Chlorine is an electron-withdrawing group, yet it exhibits ortho- and para-directing behavior in electrophilic aromatic substitution. |
Reason (R): | Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
1. | 2. | ||
3. | 4. |
1. | 2. | ||
3. | 4. |
List-I (Mixtures/Sample) |
List-II (Technique used for purification) |
||
A | Glycerol from spent lye | (I) | Steam distillation |
B | Chloroform + Aniline | (II) | Fractional distillation |
C | Fractions of crude oil | (III) | Distillation under reduced pressure |
D | Aniline+water | (IV) | Distillation |
Options: | (A) | (B) | (C) | (D) |
1. | III | IV | II | I |
2. | IV | II | I | III |
3. | I | II | III | IV |
4. | I | III | II | IV |
Statement I: | In an organic compound, when inductive and electromeric effects operate in opposite directions, the inductive effect predominates. |
Statement II: | Hyperconjugation is observed in o-xylene. |