In a mildly alkaline medium, thiosulphate ion is oxidized by MnO4- to "A". The oxidation state of sulphur in "A" is:

1. +4 2. +2
3. –2 4. +6

Subtopic:  d-Block Elements- Properties & Uses |
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In basic medium CrO42− oxidizes S2O32– to form S2O32−  to form  SO42−  and itself changes into Cr(OH)4− . The volume of 0.154 M  CrO42− required to react with 40 mL of 0.25 M S2O32− is: 

(Rounded-off to the nearest integer)

1. 178 
2. 173 
3. 169 
4. 181

Subtopic:  d-Block Elements- Properties & Uses |
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What is the outer electronic configuration of Gadolinium (\(Gd\)) with atomic number 64?
1. \(4 f^3~ 5 d^5~ 6 s^2\) 2. \(4 f^8~ 5 d^0 ~6 s^2\)
3. \(4 f^4~ 5 d^4~ 6 s^2\) 4. \(4 f^7~ 5 d^1~ 6 s^2\)
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The correct order of EoM2+/M values with a negative sign for the four successive elements Cr, Mn, Fe, and Co is:

1. Cr > Mn > Fe > Co

2. Mn > Cr > Fe > Co

3. Cr > Fe > Mn > Co

4. Fe > Mn > Cr > Co

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In context with the transition elements, which of the following statements is incorrect?

1. In addition to the normal oxidation state, the zero oxidation state is also shown by these elements in complexes.
2. In the highest oxidation states, the transition metal shows basic character and forms cationic complexes.
3. In the highest oxidation states of the first five transition elements (Sc to Mn), all the 4s and 3d electrons are used for bonding.
4. Once the d5 configuration is exceeded, the tendency to involve all the 3d electrons in bonding decreases.

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A larger number of oxidation states are exhibited by the actinoids than by the lanthanoids, the main reason being:

1. More reactive nature of the actinoids than the lanthanoids

2. More energy difference between 5f and 6d than between 4f and 5d orbitals

3. Lesser energy difference between 5f and 6d than between 4f and 5d orbitals

4. 4f orbitals more diffuse than the 5f orbitals

Subtopic:  f-Block Elements- Properties & Uses |
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If dichromate ion is treated with base, the oxidation number of Cr in the product formed will be:

1. +6

2. +4

3. +5

4. +2

Subtopic:  Chemistry of Mn and Cr Compounds |
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Which of the following lanthanoids do not form MO2 [where M is a lanthanoid metal]?

1. Pr

2. Dy

3. Nd

4. Yb

Subtopic:  Lanthanoid & Actinoids Contraction |
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On treating a compound with warm dil. H2SO4, gas X is evolved
which turns K2Cr2O7 paper acidified with dil. H2SO4 to a green compound Y.
Determine X and Y respectively:

1. X=SO2,Y=Cr2O3

2. X=SO3,Y=Cr2O3

3. X=SO2,Y=Cr2(SO4)3

4. X=SO3,Y=Cr2(SO4)3

Subtopic:  Chemistry of Mn and Cr Compounds |
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Given below are two statements:

Statement I: CeO2 can be used for the oxidation of aldehydes and ketones.

Statement II: Aqueous solution of EuSO4 is a strong reducing agent.

In the light of the above statements, choose the correct answer from the options given below:

1. Statement I is false but statement II is true

2. Statement I is true but statement II is false

3. Both statement I and statement II are true

4. Both statement I and statement II are false

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