| Statement I: | Ferromagnetism is considered as an extreme form of paramagnetism. |
| Statement II: | The number of unpaired electrons in a \(Cr^{2+}\)ion (Z = 24) is the same as that of a \(Nd^{3+}\) ion (Z = 60). |
| 1. | Statement I is True but Statement II is False. |
| 2. | Statement I is False but Statement II is True. |
| 3. | Both Statement I and Statement II are True. |
| 4. | Both Statement I and Statement II are False. |
| 1. | d5 to d2 configuration | 2. | d4 to d5 configuration |
| 3. | d3 to d5 configuration | 4. | d5 to d4 configuration |
Which of the following ions have the same 'spin-only' magnetic moment?
| A. | Ti+3 | B. | Cr2+ |
| C. | Mn2+ | D. | Fe2+ |
| E. | Sc3+ | ||
Choose the most appropriate answer from the options given below:
| 1. | A and E only | 2. | B and C only |
| 3. | A and D only | 4. | B and D only |
| List-I (Element) |
List-II (Most Common oxidation state/s) |
||
| A. | \(\mathrm{Fe}\) | I. | +2, +7 |
| B. | V | II. | +3, +2 |
| C. | \(\mathrm{Mn}\) | III. | +4 |
| D. | \(\mathrm{Ti}\) | IV. | +5 |
| 1. | A-II, B-IV, C-I, D-III | 2. | A-IV, B-II, C-I, D-III |
| 3. | A-II, B-I, C-IV, D-III | 4. | A-I, B-IV, C-II, D-III |
| 1. | C and D only | 2. | A and D only |
| 3. | A and B only | 4. | B and C only |
| 1. | \(\mathrm{Ce}^{4+} \) and \(\mathrm{Tb}^{4+}\) | 2. | \(\mathrm{La}^{3+} \) and \(\mathrm{Lu}^{3+}\) |
| 3. | \(\mathrm{Eu}^{2+} \) and \(\mathrm{Yb}^{2+}\) | 4. | \(\mathrm{Eu}^{2+} \) and \(\mathrm{Tb}^{4+}\) |
| A. | All the transition metals except scandium form MO oxides which are ionic. |
| B. | The highest oxidation number corresponds to the group number in transition metal oxides is attained in Sc2O3 to Mn2O7. |
| C. | Basic character increases from V2O3 to V2O4 to V2O5. |
| D. | V2O4 dissolves in acids to give VO43-. |
| E. | CrO is basic, but Cr2O3 is amphoteric. |
| 1. | B and C only | 2. | A and E only |
| 3. | B and D only | 4. | C and D only |
| Assertion (A): | Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. |
| Reason (R): | There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. |
| 1. | (A) is True but (R) is False |
| 2. | (A) is False but (R) is True |
| 3. | Both (A) and (R) are True and (R) is the correct explanation of (A) |
| 4. | Both (A) and (R) are True but (R) is not the correct explanation of (A) |
| 1. | The shapes of dxy, dyz, and dzx orbitals are similar to each other; and dx2 -y2 and dz2 are similar to each other. |
| 2. | All the five 5d orbitals are different in size when compared to the respective 4d orbitals. |
| 3. | All the five 4d orbitals have shapes similar to the respective 3d orbitals. |
| 4. | In an atom, all the five 3d orbitals are equal in energy in free state. |