In a reaction, A + B → Product, the rate is doubled when the concentration of B is doubled, and the rate increases by a factor of 8, when the concentrations of both the reactants (A and B) are doubled. The rate law for the reaction can be written as:
1. Rate = k[A][B]2
2. Rate = k[A]2[B]2
3. Rate = k[A][B]
4. Rate = k[A]2[B]
Which of the following statements about the order of reaction is incorrect?
| 1. | Order is not influenced by the stoichiometric coefficient of the reactants. |
| 2. | Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction. |
| 3. | The order of reaction is always a whole number. |
| 4. | Order can be determined by experiments only. |
The unit of rate constant for a zero-order reaction is:
1.
2.
3.
4.
The rate of the reaction can be written in three ways:
Find out the relationship between k and k′ and between k and k′′:
1. k′ = k, k′′= k
2. k′= 2k; k′′= k
3. k′= 2k, k′′= k/2
4. k′ = 2k; k′′= 2k
During the kinetic study of the reaction, 2A + B\( \rightarrow\)C + D, following results were obtained:
| Run | [A)/ mol L-1 | [B)/ mol L-1 | Initial rate of formation of D/mol L-1 |
| I | 0.1 | 0.1 | \(6.0 \times 10^{- 3}\) |
| II | 0.3 | 0.2 | \(7.2 \times 10^{- 2}\) |
| III | 0.3 | 0.4 | \(2.88 \times \left(10\right)^{- 1}\) |
| IV | 0.4 | 0.1 | \(2.40 \times \left(10\right)^{- 2}\) |
Based on the above data which one of the following is correct?
1. rate= k[A]2[B]
2. rate= k[A][B]
3. rate= k[A]2[B]2
4. rate= k[A][B]2
The rate of the reaction
2NO + Cl2 → 2NOCl is given by the rate equation
rate = k[NO]2[Cl2]
The value of the rate constant can be increased by:
1. Increasing the concentration of NO
2. Increasing the concentration of Cl2
3. Increasing the temperature
4. All of the above
Calculate the specific rate constant of the reaction if the half-life period of a first-order reaction is 1386 s?
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2.
3.
4.
For the reaction, A + B → products, it is observed that-
(1) On doubling the initial concentration of A only, the rate of reaction is also doubled and
(2) On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in the rate of the reaction.
The rate of this reaction is given by:
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2.
3.
4.
In the reaction,
3Br2(l)+3H2O(l)
The rate of appearance of bromine (Br2) is related to the rate of disappearance of bromide ions:
1.
2.
3.
4.