0.3780 grams of an organic chloro compound gave 0.5740 grams of silver chloride in Carius estimation. % of chlorine present in the compound is -

1. 25% 2. 37.59%
3. 42% 4. 05.70 %

Subtopic:  Quantitative Analysis of Organic Compounds |
 76%
Level 2: 60%+
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In the Carius method, 0.468 grams of an organic sulphur compound gives 0.668 grams of barium sulphate. The percentage of sulphur in the given compound is:

1. 19.59% 2. 25.40%
3. 09.24% 4. 27.59%
Subtopic:  Quantitative Analysis of Organic Compounds |
 68%
Level 2: 60%+
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The most stable carbocation among the following is-
1. \(({CH_3})_3C\overset{+}{C}H_2\)
2. \(({CH_3})_3\overset{+}{C}\)
3. \({CH_3}CH_2\overset{+}{C}H_2\)
4. \(({CH_3})\overset{+}{C}HCH_2CH_3\)

Subtopic:  Electron Displacement Effects |
 83%
Level 1: 80%+
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Why is O₂NCH₂CH₂O⁻ more stable than CH₃CH₂O⁻?

1. NOshows +I effect
2. NO2 shows -I effect
3. NO2 decreases the positive charge on the compound
4. The ethyl group increases the positive charge on the compound

Subtopic:  Electron Displacement Effects |
 88%
Level 1: 80%+
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Alkyl groups act as electron donors when attached to a π system due to:

1. Inductive effect 2. Mesomeric effect
3. Resonance 4. Hyperconjugation
Subtopic:  Electron Displacement Effects |
 50%
Level 3: 35%-60%
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An electrophile among the following is :

1. \(\mathrm{OH}^-\) 2. \(\mathrm{NC}^-\)
3. \(R_3C^-\) 4. Carbonyl group
Subtopic:  Nucleophile & Electrophile |
 74%
Level 2: 60%+
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Geometrical isomerism can be shown by:

1.
2.
3.
4.
Subtopic:  Stereo Isomers |
 90%
Level 1: 80%+
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Free radical formation will take place in :

1.
2.
3.
4.
Subtopic:  Reaction Intermediates ; Preparation & Properties |
 87%
Level 1: 80%+
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The effect that can explain the given order of acidity of the carboxylic acids is:

Cl3CCOOH > Cl2CHCOOH > ClCH2COOH

1. +I effect

2. -I effect

3. +E effect

4. -E effect

Subtopic:  Electron Displacement Effects |
 91%
Level 1: 80%+
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The purification method based on the difference in solubilities of the compound and the impurities in a solvent is -
1. Crystallisation
2. Distillation
3. Chromatography
4. Isolation

Subtopic:  Purification of Organic Compounds |
 71%
Level 2: 60%+
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