An element among the following that shows the maximum number of oxidation states is:

1. Cr

2. Fe

3. Mn

4. V

Subtopic:  d-Block Elements- Properties & Uses |
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AIPMT - 2002
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Match the following aspects with the respective metal.

               Aspects                                    Metal

(a) The metal which reveals a       (i) Scandium
     maximum number of
     oxidation states

(b) The metal although placed       (ii) Copper 
      in 3d block is considered
      not as a transition element

(c) The metal which does not         (iii) Manganese 
     exhibit variable oxidation states

(d) The metal which in +1             (iv) Zinc 
     oxidation state in aqueous
     solution undergoes
    disproportionation

Select the correct option :

(1) (a)-(i) (b)-(iv) (c)-(ii) (d)-(iii)

(2) (a)-(iii) (b)-(iv) (c)-(i) (d)-(ii)

(3) (a)-(iii) (b)-(i) (c)-(iv) (d)-(ii)

(4) (a)-(ii) (b)-(iv) (c)-(i) (d)-(iii)

Subtopic:  d-Block Elements- Properties & Uses |
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For a metal ion, \(\mu = 4.9 \ B.M\). The number of unpaired electrons present in the metal ion is:

1. 3
2. 4
3. 2
4. 1
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Assertion (A): Transition metals and their compounds are effective catalysts. 
Reason (R): They have the ability to adopt multiple oxidation states and to form complexes.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
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Gadolinium (atomic number 64) belongs to the 4f series.
The correct electronic configuration of gadolinium among the following is:

\(1. (X e) 4 f^{7} 5 d^{1} 6 s^{2} \)

2. \( (X e) 4 f^{6} 5 d^{2} 6 s^{2}\)

3. \((X e) 4 f^{8} 6 d^{2}\)

4. \((X e) 4 f^{9} 5 s^{1}\)

Subtopic:  d-Block Elements- Properties & Uses |
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The irregular variation of ionization enthalpies (first and second) in the first series of the transition elements is due to:
1. The extra stability of configurations such as d5, d10
2. The less stability of configurations such as d5, d10 
3. The extra stability of configurations such as d4, d6
4. The extra stability of configurations such as d7, d8
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The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of the transition element, which shows the highest magnetic moment.

1. 3d7 2. 3d5
3. 3d8 4. 3d2
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The reason why zinc does not exhibit variable oxidation states is:

1. inert pair effect.
2. completely filled 3d sub-shell.
3. completely filled 4s sub-shell.
4. common ion effect.
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A pair of ions that have the same electronic configuration among their constituent species is:

1. \(Sr^{3+}, Cr^{3+}\)
2. \(Fe^{3+}, Mn^{2+}\)
3. \(Fe^{3+}, Co^{3+}\)
4. \(Cr^{3+}, Fe^{3+}\)

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Which transition element does not exhibit variable oxidation states?

1. Manganese (\(Mn\))
2. Chromium(\(Cr\))
3. Scandium(\(Sc\))
4. Iron(\(Fe\))

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