| List-I (Quantitative Methods) |
List-II (Principle and reagents used) |
||
| A. | Thin Layer Chromatography | (i). | Partition Chromatography |
| B. | Yellow coloured | (ii). | Adsorption chromatography |
| C. | Paper chromatography | (iii). | Ammonia |
| D. | Kjeldahl method | (iv). | (NH4)3PO4.12MoO3 |
| A | B | C | D | |
| 1. | (iii) | (iv) | (ii) | (i) |
| 2. | (ii) | (iv) | (i) | (iii) |
| 3. | (ii) | (i) | (iv) | (iii) |
| 4. | (iii) | (iv) | (i) | (ii) |
The sodium extract of an organic compound on acidification with acetic acid and the addition of lead acetate solution gives a black precipitate.
The organic compound contains:
| 1. | Nitrogen | 2. | Halogen |
| 3. | Sulphur | 4. | Phosphorus |
The compound formed in the positive test for nitrogen with the Lassaigne solution of an organic compound is:
1. Fe4[Fe(CN)6]3
2. Na3[Fe(CN)6]
3. Fe(CN)3
4. Na4[Fe(CN)5NOS]
| Assertion (A): | Simple distillation can help in separating a mixture of propan-1-ol (boiling point 97°C ) and propanone (boiling point 56°C ). |
| Reason (R): | Liquids with a difference of more than 20°C in their boiling points can be separated by simple distillation. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| Statement I: | In the Lassaigne test, an organic compound with both N and S, responds to the test of SCN-. |
| Statement II: | In the Lassaigne test, if Na is taken in excess, it destroys SCN- and forms Na2S and NaCN. |
| 1. | Statement I is correct and Statement II is incorrect. |
| 2. | Statement I is incorrect and Statement II is correct. |
| 3. | Both Statement I and Statement II are correct. |
| 4. | Both Statement I and Statement II are incorrect. |